Copper-catalysed synthesis of α-alkylidene cyclic carbonates from propargylic alcohols and CO2

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We report a N-heterocyclic carbene copper(I) complex-catalysed formal cycloaddition between readily available propargylic alcohols and carbon dioxide at room temperature. By using the combination of a sterically demanding BPDPrCuCl complex (BPDPr = 1,3-bis(2,6-diisopropylphenyl)-1,3-diazonine-2-ylid...

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Main Authors:	Cervantes Reyes, Alejandro (Author) , Farshadfar, Kaveh (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Schaub, Thomas (Author) , Ariafard, Alireza (Author) , Hashmi, A. Stephen K. (Author)
Format:	Article (Journal)
Language:	English
Published:	2021
In:	Green chemistry Year: 2021, Volume: 23, Issue: 2, Pages: 889-897
ISSN:	1463-9270
DOI:	10.1039/D0GC03990J
Online Access:	Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D0GC03990J Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2021/gc/d0gc03990j
Author Notes:	Alejandro Cervantes-Reyes, Kaveh Farshadfar, Matthias Rudolph, Frank Rominger, Thomas Schaub, Alireza Ariafard and A. Stephen K. Hashmi

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