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A 2,2′-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenes via reversible C-P bond formation

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A metal-templated synthetic route to cyclic (aryl)(ylidic) mesoionic carbenes (CArY-MICs) featuring an endocyclic P-ylide is presented. This approach, which requires metal templates with two cis-positioned open coordination sites, is based on the controlled cyclisation of a P,P′-diisopropyl-substitu...

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Main Authors: Wagner, Hannah (Author) , Wadepohl, Hubert (Author) , Ballmann, Joachim (Author)
Format: Article (Journal)
Language:English
Published: 29 Jan 2021
In: Chemical science
Year: 2021, Volume: 12, Issue: 10, Pages: 3693-3701
ISSN:2041-6539
DOI:10.1039/D0SC06128J
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D0SC06128J
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2021/sc/d0sc06128j
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Author Notes:Hannah K. Wagner, Hubert Wadepohl and Joachim Ballmann
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Validation of ab-initio-predicted magnetic anisotropies and magneto-structural correlations in linear hetero-trinuclear DyIII-NiII2 compounds by Comba, Peter (Author) , Enders, Markus (Author) , Großhauser, Michael (Author) , Hiller, Markus (Author) , Klingeler, Rüdiger (Author) , Koo, Changhyun (Author) , Müller, Dennis (Author) , Rajaraman, Gopalan (Author) , Swain, Abinash (Author) , Tavhelidse, Msia (Author) , Wadepohl, Hubert (Author) ,


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