A 2,2′-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenes via reversible C-P bond formation
A metal-templated synthetic route to cyclic (aryl)(ylidic) mesoionic carbenes (CArY-MICs) featuring an endocyclic P-ylide is presented. This approach, which requires metal templates with two cis-positioned open coordination sites, is based on the controlled cyclisation of a P,P′-diisopropyl-substitu...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
29 Jan 2021
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| In: |
Chemical science
Year: 2021, Jahrgang: 12, Heft: 10, Pages: 3693-3701 |
| ISSN: | 2041-6539 |
| DOI: | 10.1039/D0SC06128J |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D0SC06128J Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2021/sc/d0sc06128j |
| Verfasserangaben: | Hannah K. Wagner, Hubert Wadepohl and Joachim Ballmann |
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