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A 2,2′-diphosphinotolane as a versatile precursor for the synthesis of P-ylidic mesoionic carbenes via reversible C-P bond formation

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A metal-templated synthetic route to cyclic (aryl)(ylidic) mesoionic carbenes (CArY-MICs) featuring an endocyclic P-ylide is presented. This approach, which requires metal templates with two cis-positioned open coordination sites, is based on the controlled cyclisation of a P,P′-diisopropyl-substitu...

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Autori principali: Wagner, Hannah (Autore) , Wadepohl, Hubert (Autore) , Ballmann, Joachim (Autore)
Natura: Article (Journal)
Lingua:inglese
Pubblicazione: 29 Jan 2021
In: Chemical science
Year: 2021, Volume: 12, Fascicolo: 10, Pages: 3693-3701
ISSN:2041-6539
DOI:10.1039/D0SC06128J
Accesso online:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D0SC06128J
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2021/sc/d0sc06128j
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Note sull'autore:Hannah K. Wagner, Hubert Wadepohl and Joachim Ballmann
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Validation of ab-initio-predicted magnetic anisotropies and magneto-structural correlations in linear hetero-trinuclear DyIII-NiII2 compounds di Comba, Peter (Autore) , Enders, Markus (Autore) , Großhauser, Michael (Autore) , Hiller, Markus (Autore) , Klingeler, Rüdiger (Autore) , Koo, Changhyun (Autore) , Müller, Dennis (Autore) , Rajaraman, Gopalan (Autore) , Swain, Abinash (Autore) , Tavhelidse, Msia (Autore) , Wadepohl, Hubert (Autore) ,


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