Catalytic oxidative cyclisation reactions of 1,6-enynes: a critical comparison between gold and palladium
In transition-metal catalysis, similar reactivities are often described for related metals, thereby resulting in the formation of similar/identical products. However, only in rare cases can similar/identical product be obtained by using non-related metals. Amongst these reactions is the oxidative cy...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2013
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| In: |
Israel journal of chemistry
Year: 2013, Jahrgang: 53, Heft: 11/12, Pages: 883-891 |
| ISSN: | 1869-5868 |
| DOI: | https://doi.org/10.1002/ijch.201300072 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/ijch.201300072 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ijch.201300072 
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| Verfasserangaben: | Laura Nunes dos Santos Comprido and A. Stephen K. Hashmi |
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| 520 | |a In transition-metal catalysis, similar reactivities are often described for related metals, thereby resulting in the formation of similar/identical products. However, only in rare cases can similar/identical product be obtained by using non-related metals. Amongst these reactions is the oxidative cyclisation of 1,6-enynes by using palladium or gold. Similarities and differences will be discussed with a special focus on the diastereo- and enantioselective course of the reaction. | ||
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