Cyclisation versus 1,1-carboboration: reactions of B(C6F5)3 with propargyl amides

A series of propargyl amides were prepared and their reactions with the Lewis acidic compound B(C6F5)3 were investigated. These reactions were shown to afford novel heterocycles under mild conditions. The reaction of a variety of N-substituted propargyl amides with B(C6F5)3 led to an intramolecular...

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Bibliographic Details
Main Authors: Melen, Rebecca L. (Author) , Hansmann, Max M. (Author) , Lough, Alan J. (Author) , Hashmi, A. Stephen K. (Author) , Stephan, Douglas W. (Author)
Format: Article (Journal)
Language:English
Published: 06 August 2013
In: Chemistry - a European journal
Year: 2013, Volume: 19, Issue: 36, Pages: 11928-11938
ISSN:1521-3765
DOI:https://doi.org/10.1002/chem.201301899
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/chem.201301899
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201301899
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Author Notes:Rebecca L. Melen, Max M. Hansmann, Alan J. Lough, A. Stephen K. Hashmi, and Douglas W. Stephan