Metal-reinforced bonding
It is well known that donation of electron density from a metal atom back into an empty orbital on a coordinating ligand, such as an alkene, weakens the π bond. Now, it has been shown that in a metal-diborene complex, π-backdonation involves bonding π-orbitals on the ligand and leads to B-B bond str...
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
24 January 2013
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Nature chemistry
Year: 2013, Jahrgang: 5, Heft: 2, Pages: 88-89 |
| ISSN: | 1755-4349 |
| DOI: | 10.1038/nchem.1554 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1038/nchem.1554 Verlag, lizenzpflichtig, Volltext: https://www.nature.com/articles/nchem.1554 
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| Verfasserangaben: | Hans-Jörg Himmel |
| Zusammenfassung: | It is well known that donation of electron density from a metal atom back into an empty orbital on a coordinating ligand, such as an alkene, weakens the π bond. Now, it has been shown that in a metal-diborene complex, π-backdonation involves bonding π-orbitals on the ligand and leads to B-B bond strengthening. |
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| Beschreibung: | Gesehen am 25.05.2021 |
| Beschreibung: | Online Resource |
| ISSN: | 1755-4349 |
| DOI: | 10.1038/nchem.1554 |