Cis- and trans-[SnR2] configurational isomers in diorganotin(IV) complexes containing mono or bidentate N-donor ligands
The reaction of diorganotin(IV) complexes SnR2Cl2 (R=Et, Ph) with the bidentate pyridyl ligand of 4,4′-di-tert-butyl-2,2′-bipyridine (bu2bpy) or phendione (phendione=1,10-phenanthroline-5,6-dione) resulted in the formation of the hexa-coordinated 1:1 adducts of [SnR2Cl2(NN] {R=Et, NN=bu2bpy (1); R=E...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
19 July 2013
|
| In: |
Polyhedron
Year: 2013, Jahrgang: 63, Pages: 111-116 |
| DOI: | 10.1016/j.poly.2013.07.011 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.poly.2013.07.011 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0277538713005366 
|
| Verfasserangaben: | Badri Z. Momeni, Sadegh Kheirandish, Niloofar Aghamohammadi, Vahid Noroozi, Behrouz Notash, Frank Rominger |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1758931795 | ||
| 003 | DE-627 | ||
| 005 | 20220819214218.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 210526s2013 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/j.poly.2013.07.011 |2 doi | |
| 035 | |a (DE-627)1758931795 | ||
| 035 | |a (DE-599)KXP1758931795 | ||
| 035 | |a (OCoLC)1341414469 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Momeni, Badri Z. |e VerfasserIn |0 (DE-588)1209972360 |0 (DE-627)1698037589 |4 aut | |
| 245 | 1 | 0 | |a Cis- and trans-[SnR2] configurational isomers in diorganotin(IV) complexes containing mono or bidentate N-donor ligands |c Badri Z. Momeni, Sadegh Kheirandish, Niloofar Aghamohammadi, Vahid Noroozi, Behrouz Notash, Frank Rominger |
| 246 | 3 | 0 | |a two |
| 246 | 3 | 3 | |a Cis- and trans-[SnR 2] configurational isomers in diorganotin(four) complexes containing mono or bidentate N-donor ligands |
| 264 | 1 | |c 19 July 2013 | |
| 300 | |a 6 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Titel ist die Zahl "2" tiefgestellt | ||
| 500 | |a Gesehen am 01.06.2021 | ||
| 520 | |a The reaction of diorganotin(IV) complexes SnR2Cl2 (R=Et, Ph) with the bidentate pyridyl ligand of 4,4′-di-tert-butyl-2,2′-bipyridine (bu2bpy) or phendione (phendione=1,10-phenanthroline-5,6-dione) resulted in the formation of the hexa-coordinated 1:1 adducts of [SnR2Cl2(NN] {R=Et, NN=bu2bpy (1); R=Et, NN=phendione (2); R=Ph, NN=bu2bpy (3)}. On the other hand, the reaction of SnPh2Cl2 with the corresponding monodentate ligand of 4-tert-butylpyridine (bupy) affords the 1:2 adduct of [SnPh2Cl2(bupy)2] (4). The solid state X-ray determination of complex [SnEt2Cl2(bu2bpy)] (1) revealed that the complex 1 contains the hexa- coordinated tin(IV) atom in an octahedral geometry with the trans-[SnEt2] configuration while the X-ray crystal structure determination of complex [SnPh2Cl2(bu2bpy)] (3) reveals that the tin atom is hexa-coordinated in a distorted octahedral geometry with an unusual feature of the cis-[SnPh2] configuration. On the other hand, two carbon, two chlorine and two nitrogen atoms from two pyridyl ligands form an octahedral geometry around tin(IV) atom with trans-C2, trans-N2 and trans-Cl2 configurations in [SnMe2Cl2(bupy)2] (5). The resulting products have been fully characterized by elemental analysis, multinuclear NMR (1H, 13C, 119Sn) and 2D NMR (HH- COSY, 1H-13C HMQC) spectroscopy. | ||
| 650 | 4 | |a Crystal structure | |
| 650 | 4 | |a Diorganotin | |
| 650 | 4 | |a Geometry | |
| 650 | 4 | |a Pyridyl | |
| 650 | 4 | |a Spectroscopy | |
| 700 | 1 | |a Kheirandish, Sadegh |e VerfasserIn |4 aut | |
| 700 | 1 | |a Aghamohammadi, Niloofar |e VerfasserIn |4 aut | |
| 700 | 1 | |a Noroozi, Vahid |e VerfasserIn |4 aut | |
| 700 | 1 | |a Notash, Behrouz |e VerfasserIn |4 aut | |
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Polyhedron |d Amsterdam [u.a.] : Elsevier Science, 1982 |g 63(2013) vom: Okt., Seite 111-116 |h Online-Ressource |w (DE-627)320402967 |w (DE-600)2000326-2 |w (DE-576)096704209 |7 nnas |a Cis- and trans-[SnR2] configurational isomers in diorganotin(IV) complexes containing mono or bidentate N-donor ligands |
| 773 | 1 | 8 | |g volume:63 |g year:2013 |g month:10 |g pages:111-116 |g extent:6 |a Cis- and trans-[SnR2] configurational isomers in diorganotin(IV) complexes containing mono or bidentate N-donor ligands |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.poly.2013.07.011 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://www.sciencedirect.com/science/article/pii/S0277538713005366 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20210526 | ||
| 993 | |a Article | ||
| 994 | |a 2013 | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 6 |y j | ||
| 999 | |a KXP-PPN1758931795 |e 3931166562 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"note":["Im Titel ist die Zahl \"2\" tiefgestellt","Gesehen am 01.06.2021"],"title":[{"title":"Cis- and trans-[SnR2] configurational isomers in diorganotin(IV) complexes containing mono or bidentate N-donor ligands","title_sort":"Cis- and trans-[SnR2] configurational isomers in diorganotin(IV) complexes containing mono or bidentate N-donor ligands"}],"origin":[{"dateIssuedDisp":"19 July 2013","dateIssuedKey":"2013"}],"titleAlt":[{"title":"Cis- and trans-[SnR 2] configurational isomers in diorganotin(four) complexes containing mono or bidentate N-donor ligands"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"language":["eng"],"person":[{"display":"Momeni, Badri Z.","family":"Momeni","role":"aut","given":"Badri Z."},{"given":"Sadegh","role":"aut","display":"Kheirandish, Sadegh","family":"Kheirandish"},{"family":"Aghamohammadi","display":"Aghamohammadi, Niloofar","role":"aut","given":"Niloofar"},{"given":"Vahid","role":"aut","family":"Noroozi","display":"Noroozi, Vahid"},{"display":"Notash, Behrouz","family":"Notash","given":"Behrouz","role":"aut"},{"given":"Frank","role":"aut","display":"Rominger, Frank","family":"Rominger"}],"id":{"doi":["10.1016/j.poly.2013.07.011"],"eki":["1758931795"]},"relHost":[{"id":{"eki":["320402967"],"zdb":["2000326-2"]},"physDesc":[{"extent":"Online-Ressource"}],"pubHistory":["1.1982 - 30.2011; Vol. 31.2012 -"],"recId":"320402967","origin":[{"dateIssuedDisp":"1982-","publisherPlace":"Amsterdam [u.a.]","publisher":"Elsevier Science","dateIssuedKey":"1982"}],"note":["Gesehen am 13.06.23"],"title":[{"title":"Polyhedron","title_sort":"Polyhedron","subtitle":"the international journal for inorganic and organometallic chemistry"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"part":{"year":"2013","pages":"111-116","text":"63(2013) vom: Okt., Seite 111-116","extent":"6","volume":"63"},"language":["eng"],"disp":"Cis- and trans-[SnR2] configurational isomers in diorganotin(IV) complexes containing mono or bidentate N-donor ligandsPolyhedron"}],"physDesc":[{"extent":"6 S."}],"name":{"displayForm":["Badri Z. Momeni, Sadegh Kheirandish, Niloofar Aghamohammadi, Vahid Noroozi, Behrouz Notash, Frank Rominger"]},"recId":"1758931795"} | ||
| SRT | |a MOMENIBADRCISANDTRAN1920 | ||