Environmentally friendly, photochemical access to [N^C^N] AuIII pincer complexes by oxidative addition
Starting from commercially available DMSAuCl and diazonium salts, cationic [ ]AuIII complexes were synthesized in a selective, photosensitizer-free, photochemical reaction by irradiation with blue LED light. This new protocol represents the first easy synthesis of these types of pincer complexes in...
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| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
June 16, 2021
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| In: |
Chemistry - a European journal
Year: 2021, Volume: 27, Issue: 34, Pages: 8673-8677 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.202100035 |
| Online Access: | Resolving-System, kostenfrei, Volltext: https://doi.org/10.1002/chem.202100035 Verlag, kostenfrei, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202100035 
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| Author Notes: | Daniel Eppel, Philipp Penert, Johanna Stemmer, Christina Bauer, Matthias Rudolph, Margit Brückner, Frank Rominger, and A. Stephen K. Hashmi |
MARC
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| 520 | |a Starting from commercially available DMSAuCl and diazonium salts, cationic [ ]AuIII complexes were synthesized in a selective, photosensitizer-free, photochemical reaction by irradiation with blue LED light. This new protocol represents the first easy synthesis of these types of pincer complexes in moderate to excellent yield starting from a readily available gold(I) precursor with nitrogen as the only by-product. Owing to the disadvantages of known protocols, especially the toxicity in the case of a transmetalation with mercury or the necessity for a mostly twofold excess of a gold precursor, this method offers an attractive alternative towards this kind of gold(III) complexes. In addition, the first arylated [ ]Au(III) pincer complex was synthesized by using this technology. | ||
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