Synthesis of Functionalized Pseudopeptides through Five-Component Sequential Ugi/Nucleophilic Reaction of N-Substituted 2-Alkynamides with Hydrazides
Five-component sequential Ugi/nucleophilic addition reaction of aromatic aldehydes, primary amines, propiolic acid, isocyanides, and hydrazides has been developed in order to access polyfunctional pseudopeptides. The reaction may proceed through formation of N-substituted 2-alkynamides as intermedia...
Gespeichert in:
| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
June 5, 2013
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| In: |
The journal of organic chemistry
Year: 2013, Jahrgang: 78, Heft: 13, Pages: 6450-6456 |
| ISSN: | 1520-6904 |
| DOI: | 10.1021/jo4003294 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jo4003294
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| Verfasserangaben: | Shokoofeh Maghari, Sorour Ramezanpour, Saeed Balalaie, Fatemeh Darvish, Frank Rominger, Hamid Reza Bijanzadeh |
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| 520 | |a Five-component sequential Ugi/nucleophilic addition reaction of aromatic aldehydes, primary amines, propiolic acid, isocyanides, and hydrazides has been developed in order to access polyfunctional pseudopeptides. The reaction may proceed through formation of N-substituted 2-alkynamides as intermediates. This process is found to be mild and operationally simple with broad substrate scope. | ||
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