Diastereoselective synthesis of polysubstituted cyclopentanols and cyclopentenes containing stereogenic centers via domino Michael/cyclization reaction
A highly efficient domino Michael/cyclization reaction was developed for the synthesis of cyclopentanols and cyclopentenes with four and three stereogenic centers that were generated in one-pot reaction conditions with high diastereoselectivity. The reactions proceeded through a one-pot three-compon...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
11 July 2015
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| In: |
Tetrahedron
Year: 2015, Jahrgang: 71, Heft: 38, Pages: 6860-6866 |
| ISSN: | 1464-5416 |
| DOI: | 10.1016/j.tet.2015.07.022 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.tet.2015.07.022 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0040402015010595 
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| Verfasserangaben: | S. Ahadi, Z. Naghdiani, S. Balalaie, F. Rominger |
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| 520 | |a A highly efficient domino Michael/cyclization reaction was developed for the synthesis of cyclopentanols and cyclopentenes with four and three stereogenic centers that were generated in one-pot reaction conditions with high diastereoselectivity. The reactions proceeded through a one-pot three-component reaction of β-nitrostyrenes, malononitrile and phenacyl bromide derivatives in basic media at room temperature. | ||
| 650 | 4 | |a Cyclopentanol | |
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| 650 | 4 | |a Diastereoselective | |
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