Zirconium hydrazinediido complexes derived from cyclic hydrazines and their role in the catalytic synthesis of 1,7-annulated indoles
Reaction of cyclic 1,1′-disubstituted hydrazines with the bis(dimethylamido)zirconium complex [Zr{(NXyl)2Npy} (NMe2)2] (1) in the presence of dmap yielded the hexacoordinate zirconium hydrazinediido complexes [Zr{(NXyl)2Npy}(═NNC9H10)(dmap)2] (2) and [Zr{(NXyl)2Npy}(═NNC12H8)(dmap)2] (3). Hydrazined...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
January 27, 2013
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| In: |
Organometallics
Year: 2013, Jahrgang: 32, Heft: 3, Pages: 937-940 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om301235d |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om301235d
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| Verfasserangaben: | Solveig A. Scholl, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a Reaction of cyclic 1,1′-disubstituted hydrazines with the bis(dimethylamido)zirconium complex [Zr{(NXyl)2Npy} (NMe2)2] (1) in the presence of dmap yielded the hexacoordinate zirconium hydrazinediido complexes [Zr{(NXyl)2Npy}(═NNC9H10)(dmap)2] (2) and [Zr{(NXyl)2Npy}(═NNC12H8)(dmap)2] (3). Hydrazinediides are thought to be key intermediates in the zirconium-catalyzed reaction of cyclic 1,1′-disubstituted hydrazines and disubstituted alkynes to yield 1,7-annulated indoles. Their basic structural motif is found in 5-HT3 receptor antagonists such as Cilansetron. | ||
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