Gold-catalyzed highly diastereoselective aynthesis of functionalized 3,4-disubstituted butyrolactams via phosphatyloxy or carbonate double migrations
A gold-catalyzed highly diastereoselective synthesis of functionalised 3,4-disubstituted butyrolactams via phosphatyloxy or carbonate double migrations is reported, which is proposed to proceed by a tandem 1,3-phosphatyloxy or carbonate migration and a “long-range” 1,5-phosphatyloxy or carbonate mig...
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| Main Authors: | , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
12 July 2013
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| In: |
Advanced synthesis & catalysis
Year: 2013, Volume: 355, Issue: 10, Pages: 2037-2043 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201300158 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201300158 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201300158 |
| Author Notes: | Weibo Yang, Yang Yu, Tuo Zhang, Max M. Hansmann, Daniel Pflästerer, and A. Stephen K. Hashmi |
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| 520 | |a A gold-catalyzed highly diastereoselective synthesis of functionalised 3,4-disubstituted butyrolactams via phosphatyloxy or carbonate double migrations is reported, which is proposed to proceed by a tandem 1,3-phosphatyloxy or carbonate migration and a “long-range” 1,5-phosphatyloxy or carbonate migration, which overall corresponds to a formal 1,6-migration. | ||
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