Synthesis and structural characterization of a lithium alkynyl(hydrazinediido)zirconate and its protonolysis to an alkynylhydrazido(1-)zirconium complex
Reaction of the hydrazinediido complex 1 with lithiated phenylacetylene selectively gave the lithium alkynyl(hydrazinediido)zirconate [(N2TBSNpy)Zrμ-NNPh2-1κN:2κNμ-PhCC-1κC:2κC-Li(py)] (2), which reacted with one molar equivalent of TMEDA to give the corresponding Li-TMEDA derivative [(N2TBSNpy)Zrμ-...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2015
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| In: |
Zeitschrift für anorganische und allgemeine Chemie
Year: 2015, Volume: 641, Issue: 1, Pages: 40-44 |
| ISSN: | 1521-3749 |
| DOI: | 10.1002/zaac.201400060 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/zaac.201400060 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.201400060 
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| Author Notes: | Thorsten Gehrmann, Hubert Wadepohl, and Lutz H. Gade |
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| 245 | 1 | 0 | |a Synthesis and structural characterization of a lithium alkynyl(hydrazinediido)zirconate and its protonolysis to an alkynylhydrazido(1-)zirconium complex |c Thorsten Gehrmann, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a Reaction of the hydrazinediido complex 1 with lithiated phenylacetylene selectively gave the lithium alkynyl(hydrazinediido)zirconate [(N2TBSNpy)Zrμ-NNPh2-1κN:2κNμ-PhCC-1κC:2κC-Li(py)] (2), which reacted with one molar equivalent of TMEDA to give the corresponding Li-TMEDA derivative [(N2TBSNpy)Zrμ-NNPh2-1κN:2κNμ-PhCC-1κC:2κC-Li(TMEDA)] (3). The details of the molecular structure of complex 3 were established by single-crystal X-ray structure analysis. The lithium hydrazinediidozirconate 2 was treated with triethylammonium hydrochloride yielding the corresponding alkinylzirconium hydrazido(1-) complex 4 as a mixture of two diastereomers. | ||
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| 650 | 4 | |a Hydrazides | |
| 650 | 4 | |a Lithium | |
| 650 | 4 | |a Zirconium | |
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