Site-selective oxidation of monolayered liquid-exfoliated WS2 by shielding the basal plane through adsorption of a facial amphiphile
In recent years, various functionalization strategies for transition-metal dichalcogenides have been explored to tailor the properties of materials and to provide anchor points for the fabrication of hybrid structures. Herein, new insights into the role of the surfactant in functionalization reactio...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
June 25, 2020
|
| In: |
Angewandte Chemie. International edition
Year: 2020, Jahrgang: 59, Heft: 33, Pages: 13785-13792 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202005730 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.202005730 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202005730 
|
| Verfasserangaben: | Sebastian Grieger, Beata M. Szydłowska, Vaishnavi J. Rao, Eva Steinmann, Marcus Dodds, Zahra Gholamvand, Georg S. Duesberg, Jana Zaumseil, and Claudia Backes |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1767256086 | ||
| 003 | DE-627 | ||
| 005 | 20250224161922.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 210818s2020 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1002/anie.202005730 |2 doi | |
| 035 | |a (DE-627)1767256086 | ||
| 035 | |a (DE-599)KXP1767256086 | ||
| 035 | |a (OCoLC)1295680597 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Grieger, Sebastian |d 1991- |e VerfasserIn |0 (DE-588)1050469704 |0 (DE-627)785164553 |0 (DE-576)404768504 |4 aut | |
| 245 | 1 | 0 | |a Site-selective oxidation of monolayered liquid-exfoliated WS2 by shielding the basal plane through adsorption of a facial amphiphile |c Sebastian Grieger, Beata M. Szydłowska, Vaishnavi J. Rao, Eva Steinmann, Marcus Dodds, Zahra Gholamvand, Georg S. Duesberg, Jana Zaumseil, and Claudia Backes |
| 246 | 3 | 3 | |a Site-selective oxidation of monolayered liquid-exfoliated WS 2 by shielding the basal plane through adsorption of a facial amphiphile |
| 264 | 1 | |c June 25, 2020 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Titel ist "2" tiefgestellt | ||
| 500 | |a Gesehen am 18.08.2021 | ||
| 520 | |a In recent years, various functionalization strategies for transition-metal dichalcogenides have been explored to tailor the properties of materials and to provide anchor points for the fabrication of hybrid structures. Herein, new insights into the role of the surfactant in functionalization reactions are described. Using the spontaneous reaction of WS2 with chloroauric acid as a model reaction, the regioselective formation of gold nanoparticles on WS2 is shown to be heavily dependent on the surfactant employed. A simple model is developed to explain the role of the chosen surfactant in this heterogeneous functionalization reaction. The surfactant coverage is identified as the crucial element that governs the dominant reaction pathway and therefore can severely alter the reaction outcome. This study shows the general importance of the surfactant choice and how detrimental or beneficial a certain surfactant can be to the desired functionalization. | ||
| 650 | 4 | |a functionalization | |
| 650 | 4 | |a layered compounds | |
| 650 | 4 | |a nanostructures | |
| 650 | 4 | |a surfactants | |
| 650 | 4 | |a transition-metal dichalcogenides | |
| 700 | 1 | |a Szydłowska, Beata Maria |e VerfasserIn |0 (DE-588)1188646524 |0 (DE-627)1667614665 |4 aut | |
| 700 | 1 | |a Rao, Vaishnavi J. |d 1993- |e VerfasserIn |0 (DE-588)1208018574 |0 (DE-627)1694320448 |4 aut | |
| 700 | 1 | |a Steinmann, Eva |e VerfasserIn |4 aut | |
| 700 | 1 | |a Dodds, Marcus |d 1994- |e VerfasserIn |0 (DE-588)1239193165 |0 (DE-627)1767259840 |4 aut | |
| 700 | 1 | |a Gholamvand, Zahra |e VerfasserIn |4 aut | |
| 700 | 1 | |a Duesberg, Georg S. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zaumseil, Jana |e VerfasserIn |0 (DE-588)1137235659 |0 (DE-627)894232657 |0 (DE-576)491184247 |4 aut | |
| 700 | 1 | |a Backes, Claudia |d 1982- |e VerfasserIn |0 (DE-588)1019617233 |0 (DE-627)685502767 |0 (DE-576)358450535 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Angewandte Chemie. International edition |d Weinheim : Wiley-VCH, 1998 |g 59(2020), 33 vom: 10. Aug., Seite 13785-13792 |h Online-Ressource |w (DE-627)320497879 |w (DE-600)2011836-3 |w (DE-576)111552060 |x 1521-3773 |7 nnas |a Site-selective oxidation of monolayered liquid-exfoliated WS2 by shielding the basal plane through adsorption of a facial amphiphile |
| 773 | 1 | 8 | |g volume:59 |g year:2020 |g number:33 |g day:10 |g month:08 |g pages:13785-13792 |g extent:8 |a Site-selective oxidation of monolayered liquid-exfoliated WS2 by shielding the basal plane through adsorption of a facial amphiphile |
| 856 | 4 | 0 | |u https://doi.org/10.1002/anie.202005730 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202005730 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20210818 | ||
| 993 | |a Article | ||
| 994 | |a 2020 | ||
| 998 | |g 1019617233 |a Backes, Claudia |m 1019617233:Backes, Claudia |d 120000 |d 120300 |e 120000PB1019617233 |e 120300PB1019617233 |k 0/120000/ |k 1/120000/120300/ |p 9 |y j | ||
| 998 | |g 1137235659 |a Zaumseil, Jana |m 1137235659:Zaumseil, Jana |d 120000 |d 120300 |e 120000PZ1137235659 |e 120300PZ1137235659 |k 0/120000/ |k 1/120000/120300/ |p 8 | ||
| 998 | |g 1239193165 |a Dodds, Marcus |m 1239193165:Dodds, Marcus |d 120000 |e 120000PD1239193165 |k 0/120000/ |p 5 | ||
| 998 | |g 1208018574 |a Rao, Vaishnavi J. |m 1208018574:Rao, Vaishnavi J. |d 120000 |e 120000PR1208018574 |k 0/120000/ |p 3 | ||
| 998 | |g 1188646524 |a Szydłowska, Beata Maria |m 1188646524:Szydłowska, Beata Maria |d 120000 |d 120300 |e 120000PS1188646524 |e 120300PS1188646524 |k 0/120000/ |k 1/120000/120300/ |p 2 | ||
| 998 | |g 1050469704 |a Grieger, Sebastian |m 1050469704:Grieger, Sebastian |d 120000 |d 120300 |e 120000PG1050469704 |e 120300PG1050469704 |k 0/120000/ |k 1/120000/120300/ |p 1 |x j | ||
| 999 | |a KXP-PPN1767256086 |e 3969669472 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"note":["Im Titel ist \"2\" tiefgestellt","Gesehen am 18.08.2021"],"language":["eng"],"recId":"1767256086","origin":[{"dateIssuedKey":"2020","dateIssuedDisp":"June 25, 2020"}],"name":{"displayForm":["Sebastian Grieger, Beata M. Szydłowska, Vaishnavi J. Rao, Eva Steinmann, Marcus Dodds, Zahra Gholamvand, Georg S. Duesberg, Jana Zaumseil, and Claudia Backes"]},"titleAlt":[{"title":"Site-selective oxidation of monolayered liquid-exfoliated WS 2 by shielding the basal plane through adsorption of a facial amphiphile"}],"person":[{"given":"Sebastian","role":"aut","display":"Grieger, Sebastian","family":"Grieger"},{"display":"Szydłowska, Beata Maria","family":"Szydłowska","given":"Beata Maria","role":"aut"},{"given":"Vaishnavi J.","role":"aut","display":"Rao, Vaishnavi J.","family":"Rao"},{"given":"Eva","role":"aut","display":"Steinmann, Eva","family":"Steinmann"},{"given":"Marcus","role":"aut","display":"Dodds, Marcus","family":"Dodds"},{"family":"Gholamvand","display":"Gholamvand, Zahra","role":"aut","given":"Zahra"},{"family":"Duesberg","display":"Duesberg, Georg S.","role":"aut","given":"Georg S."},{"display":"Zaumseil, Jana","family":"Zaumseil","given":"Jana","role":"aut"},{"display":"Backes, Claudia","family":"Backes","given":"Claudia","role":"aut"}],"id":{"doi":["10.1002/anie.202005730"],"eki":["1767256086"]},"type":{"bibl":"article-journal","media":"Online-Ressource"},"relHost":[{"pubHistory":["37.1998 -"],"origin":[{"dateIssuedKey":"1998","dateIssuedDisp":"1998-","publisher":"Wiley-VCH","publisherPlace":"Weinheim"}],"recId":"320497879","note":["Gesehen am 20.12.2022","Fortsetzung der Druck-Ausgabe"],"language":["eng"],"corporate":[{"role":"isb","display":"Gesellschaft Deutscher Chemiker"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title_sort":"Angewandte Chemie","partname":"International edition","title":"Angewandte Chemie","subtitle":"a journal of the Gesellschaft Deutscher Chemiker"}],"id":{"issn":["1521-3773"],"eki":["320497879"],"doi":["10.1002/(ISSN)1521-3773"],"zdb":["2011836-3"]},"part":{"year":"2020","text":"59(2020), 33 vom: 10. Aug., Seite 13785-13792","volume":"59","extent":"8","issue":"33","pages":"13785-13792"},"titleAlt":[{"title":"Angewandte Chemie / International edition"}],"disp":"Site-selective oxidation of monolayered liquid-exfoliated WS2 by shielding the basal plane through adsorption of a facial amphiphileAngewandte Chemie. International edition"}],"title":[{"title":"Site-selective oxidation of monolayered liquid-exfoliated WS2 by shielding the basal plane through adsorption of a facial amphiphile","title_sort":"Site-selective oxidation of monolayered liquid-exfoliated WS2 by shielding the basal plane through adsorption of a facial amphiphile"}],"physDesc":[{"extent":"8 S."}]} | ||
| SRT | |a GRIEGERSEBSITESELECT2520 | ||