(Aza)pentacenes clipped into a ring: stabilization of large (aza)acenes
A doubly alkylene bridged 6,13-diphenylpentacene and analogously bridged azapentacenes were prepared; they are persistent. The doubly bridged azapentacenes display superior photochemical, oxidative and thermal stabilities compared to azapentacenes protected by bis(TIPS-ethynyl)-substituents—clipping...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
April 19, 2021
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| In: |
Angewandte Chemie. International edition
Year: 2021, Jahrgang: 60, Heft: 17, Pages: 9270-9273 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202015348 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/anie.202015348 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202015348 |
| Verfasserangaben: | Lukas Ahrens, Olena Tverskoy, Svenja Weigold, Michael Ganschow, Frank Rominger, Jan Freudenberg, and Uwe H.F. Bunz |
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| 520 | |a A doubly alkylene bridged 6,13-diphenylpentacene and analogously bridged azapentacenes were prepared; they are persistent. The doubly bridged azapentacenes display superior photochemical, oxidative and thermal stabilities compared to azapentacenes protected by bis(TIPS-ethynyl)-substituents—clipping an azaacene into a large ring is a viable complement in stabilization. | ||
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