Buchumschlag

Stable N,N’-diarylated dihydrodiazaacene radical cations

Three stable N,N’-diarylated dihydroazaacene radical cations were prepared by oxidation of neutral N,N’-diarylated dihydroazaacenes synthesized via palladium-catalyzed Buchwald-Hartwig aminations of aryl iodides with N,N’-dihydroazaacenes. Both neutral as well as oxidized species were investigated v...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Xie, Gaozhan (VerfasserIn) , Bojanowski, Maximilian (VerfasserIn) , Brosius, Victor (VerfasserIn) , Wiesner, Thomas (VerfasserIn) , Rominger, Frank (VerfasserIn) , Freudenberg, Jan (VerfasserIn) , Bunz, Uwe H. F. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2021
In: Chemistry - a European journal
Year: 2021, Jahrgang: 27, Heft: 6, Pages: 1976-1980
ISSN:1521-3765
DOI:10.1002/chem.202004548
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202004548
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202004548
Volltext
Verfasserangaben:Gaozhan Xie, N. Maximilian Bojanowski, Victor Brosius, Thomas Wiesner, Frank Rominger, Jan Freudenberg, and Uwe H.F. Bunz

MARC

LEADER 00000caa a2200000 c 4500
001 1770926488
003 DE-627
005 20230426195539.0
007 cr uuu---uuuuu
008 210918s2021 xx |||||o 00| ||eng c
024 7 |a 10.1002/chem.202004548  |2 doi 
035 |a (DE-627)1770926488 
035 |a (DE-599)KXP1770926488 
035 |a (OCoLC)1295678796 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Xie, Gaozhan  |d 1990-  |e VerfasserIn  |0 (DE-588)1208029126  |0 (DE-627)1694327493  |4 aut 
245 1 0 |a Stable N,N’-diarylated dihydrodiazaacene radical cations  |c Gaozhan Xie, N. Maximilian Bojanowski, Victor Brosius, Thomas Wiesner, Frank Rominger, Jan Freudenberg, and Uwe H.F. Bunz 
264 1 |c 2021 
300 |a 5 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a First published: 30 December 2020 
500 |a Gesehen am 18.09.2021 
520 |a Three stable N,N’-diarylated dihydroazaacene radical cations were prepared by oxidation of neutral N,N’-diarylated dihydroazaacenes synthesized via palladium-catalyzed Buchwald-Hartwig aminations of aryl iodides with N,N’-dihydroazaacenes. Both neutral as well as oxidized species were investigated via UV-vis spectroscopy, single crystal analysis, and DFT calculations. All the radical cations are surprisingly stable—their absorption spectra in dichloromethane remain unchanged in ambient conditions for at least 24 hours. 
650 4 |a DFT calculations 
650 4 |a N 
650 4 |a N’-diaryldiazaacenes 
650 4 |a radical cation 
650 4 |a single crystal structure 
650 4 |a UV/Vis spectroscopy 
700 1 |a Bojanowski, Maximilian  |d 1991-  |e VerfasserIn  |0 (DE-588)1162299134  |0 (DE-627)102581987X  |0 (DE-576)507321197  |4 aut 
700 1 |a Brosius, Victor  |d 1992-  |e VerfasserIn  |0 (DE-588)1182264506  |0 (DE-627)1662600534  |4 aut 
700 1 |a Wiesner, Thomas  |d 1994-  |e VerfasserIn  |0 (DE-588)1241413991  |0 (DE-627)1770926461  |4 aut 
700 1 |a Rominger, Frank  |d 1964-  |e VerfasserIn  |0 (DE-588)1019978228  |0 (DE-627)691067821  |0 (DE-576)359202756  |4 aut 
700 1 |a Freudenberg, Jan  |d 1988-  |e VerfasserIn  |0 (DE-588)1093219564  |0 (DE-627)853188386  |0 (DE-576)462642615  |4 aut 
700 1 |a Bunz, Uwe H. F.  |d 1963-  |e VerfasserIn  |0 (DE-588)1080488456  |0 (DE-627)844723223  |0 (DE-576)181112833  |4 aut 
773 0 8 |i Enthalten in  |t Chemistry - a European journal  |d Weinheim : Wiley-VCH, 1995  |g 27(2021), 6, Seite 1976-1980  |h Online-Ressource  |w (DE-627)270935193  |w (DE-600)1478547-X  |w (DE-576)078707404  |x 1521-3765  |7 nnas  |a Stable N,N’-diarylated dihydrodiazaacene radical cations 
773 1 8 |g volume:27  |g year:2021  |g number:6  |g pages:1976-1980  |g extent:5  |a Stable N,N’-diarylated dihydrodiazaacene radical cations 
856 4 0 |u https://doi.org/10.1002/chem.202004548  |x Verlag  |x Resolving-System  |z kostenfrei  |3 Volltext 
856 4 0 |u https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202004548  |x Verlag  |z kostenfrei  |3 Volltext 
951 |a AR 
992 |a 20210918 
993 |a Article 
994 |a 2021 
998 |g 1080488456  |a Bunz, Uwe H. F.  |m 1080488456:Bunz, Uwe H. F.  |d 120000  |d 120100  |e 120000PB1080488456  |e 120100PB1080488456  |k 0/120000/  |k 1/120000/120100/  |p 7  |y j 
998 |g 1093219564  |a Freudenberg, Jan  |m 1093219564:Freudenberg, Jan  |d 120000  |d 120100  |e 120000PF1093219564  |e 120100PF1093219564  |k 0/120000/  |k 1/120000/120100/  |p 6 
998 |g 1019978228  |a Rominger, Frank  |m 1019978228:Rominger, Frank  |d 120000  |d 120100  |e 120000PR1019978228  |e 120100PR1019978228  |k 0/120000/  |k 1/120000/120100/  |p 5 
998 |g 1241413991  |a Wiesner, Thomas  |m 1241413991:Wiesner, Thomas  |d 500000  |d 501249  |e 500000PW1241413991  |e 501249PW1241413991  |k 0/500000/  |k 1/500000/501249/  |p 4 
998 |g 1182264506  |a Brosius, Victor  |m 1182264506:Brosius, Victor  |d 120000  |d 120100  |e 120000PB1182264506  |e 120100PB1182264506  |k 0/120000/  |k 1/120000/120100/  |p 3 
998 |g 1162299134  |a Bojanowski, Maximilian  |m 1162299134:Bojanowski, Maximilian  |d 120000  |d 120100  |e 120000PB1162299134  |e 120100PB1162299134  |k 0/120000/  |k 1/120000/120100/  |p 2 
999 |a KXP-PPN1770926488  |e 3979231410 
BIB |a Y 
SER |a journal 
JSO |a {"language":["eng"],"type":{"media":"Online-Ressource","bibl":"article-journal"},"note":["First published: 30 December 2020","Gesehen am 18.09.2021"],"origin":[{"dateIssuedKey":"2021","dateIssuedDisp":"2021"}],"title":[{"title_sort":"Stable N,N’-diarylated dihydrodiazaacene radical cations","title":"Stable N,N’-diarylated dihydrodiazaacene radical cations"}],"person":[{"display":"Xie, Gaozhan","family":"Xie","given":"Gaozhan","role":"aut"},{"display":"Bojanowski, Maximilian","family":"Bojanowski","role":"aut","given":"Maximilian"},{"family":"Brosius","display":"Brosius, Victor","given":"Victor","role":"aut"},{"role":"aut","given":"Thomas","display":"Wiesner, Thomas","family":"Wiesner"},{"family":"Rominger","display":"Rominger, Frank","role":"aut","given":"Frank"},{"role":"aut","given":"Jan","display":"Freudenberg, Jan","family":"Freudenberg"},{"family":"Bunz","display":"Bunz, Uwe H. F.","given":"Uwe H. F.","role":"aut"}],"id":{"doi":["10.1002/chem.202004548"],"eki":["1770926488"]},"relHost":[{"physDesc":[{"extent":"Online-Ressource"}],"pubHistory":["1.1995 -"],"recId":"270935193","id":{"zdb":["1478547-X"],"eki":["270935193"],"issn":["1521-3765"],"doi":["10.1002/(ISSN)1521-3765"]},"disp":"Stable N,N’-diarylated dihydrodiazaacene radical cationsChemistry - a European journal","note":["Fortsetzung der Druck-Ausgabe","Gesehen am 27. Februar 2017"],"title":[{"title":"Chemistry - a European journal","title_sort":"Chemistry - a European journal"}],"origin":[{"publisherPlace":"Weinheim","dateIssuedDisp":"1995-","dateIssuedKey":"1995","publisher":"Wiley-VCH"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"part":{"extent":"5","volume":"27","year":"2021","text":"27(2021), 6, Seite 1976-1980","pages":"1976-1980","issue":"6"},"language":["eng"]}],"recId":"1770926488","physDesc":[{"extent":"5 S."}],"name":{"displayForm":["Gaozhan Xie, N. Maximilian Bojanowski, Victor Brosius, Thomas Wiesner, Frank Rominger, Jan Freudenberg, and Uwe H.F. Bunz"]}} 
SRT |a XIEGAOZHANSTABLENNDI2021 

Ähnliche Einträge