Cover Image

Fused π-extended truxenes via a threefold borylation as the key step

On the basis of a threefold borylated truxene, which is accessible in high yields by iridium-catalyzed borylation under CH-activation, fused π-extended truxenes have been synthesized by a two-step method of first Suzuki-Miyaura cross-coupling reaction and subsequent condensation reaction. The mild c...

Full description

Saved in:
Bibliographic Details
Main Authors: Zhang, Gang (Author) , Rominger, Frank (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: 02 February 2016
In: Chemistry - a European journal
Year: 2016, Volume: 22, Issue: 9, Pages: 3084-3093
ISSN:1521-3765
DOI:10.1002/chem.201504621
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201504621
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201504621
Get full text
Author Notes:Gang Zhang, Frank Rominger, and Michael Mastalerz

MARC

LEADER 00000caa a2200000 c 4500
001 1772287075
003 DE-627
005 20230427055833.0
007 cr uuu---uuuuu
008 211004s2016 xx |||||o 00| ||eng c
024 7 |a 10.1002/chem.201504621  |2 doi 
035 |a (DE-627)1772287075 
035 |a (DE-599)KXP1772287075 
035 |a (OCoLC)1341421611 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Zhang, Gang  |e VerfasserIn  |0 (DE-588)1210714280  |0 (DE-627)169867774X  |4 aut 
245 1 0 |a Fused π-extended truxenes via a threefold borylation as the key step  |c Gang Zhang, Frank Rominger, and Michael Mastalerz 
246 3 3 |a Fused pi-extended truxenes via a threefold borylation as the key step 
264 1 |c 02 February 2016 
300 |a 10 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 04.10.2021 
520 |a On the basis of a threefold borylated truxene, which is accessible in high yields by iridium-catalyzed borylation under CH-activation, fused π-extended truxenes have been synthesized by a two-step method of first Suzuki-Miyaura cross-coupling reaction and subsequent condensation reaction. The mild condensation method tolerates the presence of a variety of functional groups, such as nitro, fluoro, or carboxyl moieties. Furthermore, by using this approach, N- and S-heteroarene analogues become accessible for the first time, as well as larger structures that represent derivatives of precursors for fullerene C60 or buckybowls. The attached tert-butyl groups make all derivatives sufficiently soluble to allow full spectroscopic and electrochemical investigations. Postfunctionalization of selected derivatives for further synthetic applications of the compounds is also presented. 
650 4 |a aromaticity 
650 4 |a boron 
650 4 |a cross-coupling 
650 4 |a fullerenes 
650 4 |a heterocycles 
700 1 |a Rominger, Frank  |d 1964-  |e VerfasserIn  |0 (DE-588)1019978228  |0 (DE-627)691067821  |0 (DE-576)359202756  |4 aut 
700 1 |a Mastalerz, Michael  |d 1972-  |e VerfasserIn  |0 (DE-588)130559431  |0 (DE-627)503822701  |0 (DE-576)298267950  |4 aut 
773 0 8 |i Enthalten in  |t Chemistry - a European journal  |d Weinheim : Wiley-VCH, 1995  |g 22(2016), 9, Seite 3084-3093  |h Online-Ressource  |w (DE-627)270935193  |w (DE-600)1478547-X  |w (DE-576)078707404  |x 1521-3765  |7 nnas  |a Fused π-extended truxenes via a threefold borylation as the key step 
773 1 8 |g volume:22  |g year:2016  |g number:9  |g pages:3084-3093  |g extent:10  |a Fused π-extended truxenes via a threefold borylation as the key step 
856 4 0 |u https://doi.org/10.1002/chem.201504621  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201504621  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20211004 
993 |a Article 
994 |a 2016 
998 |g 130559431  |a Mastalerz, Michael  |m 130559431:Mastalerz, Michael  |d 120000  |d 120100  |e 120000PM130559431  |e 120100PM130559431  |k 0/120000/  |k 1/120000/120100/  |p 3  |y j 
998 |g 1019978228  |a Rominger, Frank  |m 1019978228:Rominger, Frank  |d 120000  |d 120100  |e 120000PR1019978228  |e 120100PR1019978228  |k 0/120000/  |k 1/120000/120100/  |p 2 
998 |g 1210714280  |a Zhang, Gang  |m 1210714280:Zhang, Gang  |p 1  |x j 
999 |a KXP-PPN1772287075  |e 3983636519 
BIB |a Y 
SER |a journal 
JSO |a {"note":["Gesehen am 04.10.2021"],"titleAlt":[{"title":"Fused pi-extended truxenes via a threefold borylation as the key step"}],"relHost":[{"title":[{"title":"Chemistry - a European journal","title_sort":"Chemistry - a European journal"}],"note":["Fortsetzung der Druck-Ausgabe","Gesehen am 27. Februar 2017"],"type":{"media":"Online-Ressource","bibl":"periodical"},"physDesc":[{"extent":"Online-Ressource"}],"pubHistory":["1.1995 -"],"language":["eng"],"origin":[{"publisherPlace":"Weinheim","dateIssuedDisp":"1995-","publisher":"Wiley-VCH","dateIssuedKey":"1995"}],"id":{"doi":["10.1002/(ISSN)1521-3765"],"zdb":["1478547-X"],"issn":["1521-3765"],"eki":["270935193"]},"part":{"extent":"10","text":"22(2016), 9, Seite 3084-3093","pages":"3084-3093","volume":"22","year":"2016","issue":"9"},"recId":"270935193","disp":"Fused π-extended truxenes via a threefold borylation as the key stepChemistry - a European journal"}],"person":[{"role":"aut","given":"Gang","family":"Zhang","display":"Zhang, Gang"},{"display":"Rominger, Frank","family":"Rominger","given":"Frank","role":"aut"},{"display":"Mastalerz, Michael","family":"Mastalerz","role":"aut","given":"Michael"}],"title":[{"title":"Fused π-extended truxenes via a threefold borylation as the key step","title_sort":"Fused π-extended truxenes via a threefold borylation as the key step"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"physDesc":[{"extent":"10 S."}],"language":["eng"],"id":{"eki":["1772287075"],"doi":["10.1002/chem.201504621"]},"origin":[{"dateIssuedDisp":"02 February 2016","dateIssuedKey":"2016"}],"name":{"displayForm":["Gang Zhang, Frank Rominger, and Michael Mastalerz"]},"recId":"1772287075"} 
SRT |a ZHANGGANGRFUSEDEXTEN0220 

Similar Items