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Gold catalysis: β-ketonaphthalenes via molecular gymnastics of 1,6-diyne-4-en-3-ols

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1,6-Diyne-4-en-3-ols with one terminal alkyne were applied as test substrates for a possible dual catalyzed cyclization. Instead of a dual catalysis cycle, naphthyl ketone derivatives were obtained as single products. The regioselectivity of the obtained products is unprecedented. Instead of the exp...

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Main Authors: Lauterbach, Tobias (Author) , Arndt, Sebastian (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: June 4, 2013
In: Advanced synthesis & catalysis
Year: 2013, Volume: 355, Issue: 9, Pages: 1755-1761
ISSN:1615-4169
DOI:10.1002/adsc.201300396
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201300396
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201300396
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Author Notes:Tobias Lauterbach, Sebastian Arndt, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
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Sequentially rhodium-catalyzed enantioselective cycloisomerization-hydrogenation syntheses of alkylidene butyrolactone β-hydroxyethanes and alkylidene tetrahydrofuran β-aminoethane... by Muschelknautz, Nadine (Author) , Rominger, Frank (Author) , Müller, Thomas J. J. (Author) ,


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Gold catalysis: β-​ketonaphthalenes via molecular gymnastics of 1,​6-​diyne-​4-​en-​3-​ols by Lauterbach, Tobias (Author) , Arndt, Sebastian (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author) ,


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