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A giant [8+12] boronic ester cage with 48 terminal alkene units in the periphery for postsynthetic alkene metathesis

Dynamic covalent chemistry (DCC) is a powerful synthetic tool to construct large defined molecules in one step from rather simple precursors. The advantage of the intrinsic dynamics of the applied reversible reaction steps is a self-correction under the chosen conditions, to achieve high yields of t...

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Bibliographic Details
Main Authors: Hähsler, Martin (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: 2021
In: Chemistry - a European journal
Year: 2021, Volume: 27, Issue: 1, Pages: 233-237
ISSN:1521-3765
DOI:10.1002/chem.202003675
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202003675
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202003675
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Author Notes:Martin Hähsler and Michael Mastalerz

MARC

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520 |a Dynamic covalent chemistry (DCC) is a powerful synthetic tool to construct large defined molecules in one step from rather simple precursors. The advantage of the intrinsic dynamics of the applied reversible reaction steps is a self-correction under the chosen conditions, to achieve high yields of the target compound. To date, only a few examples are known, in which DCC was used to build up a molecular defined but larger product that was chemically transferred to a more stable congener in a second (irreversible) step. Here, we present a nanometer-sized [8+12] boronic ester cage containing 48 peripheral terminal alkene units which allows to put a hydrocarbon exoskeleton around the cage via alkene metathesis. 
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