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Metal-ligand cooperativity of the calix(4)pyrrolato aluminate: triggerable C-C bond formation and rate control in catalysis

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Metal-ligand cooperativity (MLC) had a remarkable impact on transition metal chemistry and catalysis. By use of the calix[4]pyrrolato aluminate, [1]−, which features a square-planar AlIII, we transfer this concept into the p-block and fully elucidate its mechanisms by experiment and theory. Compleme...

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Main Authors: Ebner, Fabian (Author) , Sigmund, Lukas M. (Author) , Greb, Lutz (Author)
Format: Article (Journal)
Language:English
Published: September 21, 2020
In: Angewandte Chemie
Year: 2020, Volume: 132, Issue: 39, Pages: 17266-17272
ISSN:1521-3757
DOI:10.1002/ange.202007717
Online Access:Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ange.202007717
Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202007717
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Author Notes:Fabian Ebner, Lukas Maximilian Sigmund und Lutz Greb
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Metal-ligand cooperativity of the calix(4)pyrrolato aluminate: triggerable C-C bond formation and rate control in catalysis by Ebner, Fabian (Author) , Sigmund, Lukas M. (Author) , Greb, Lutz (Author) ,


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