Phosphorus-containing dibenzonaphthanthrenes: electronic fine tuning of polycyclic aromatic hydrocarbons through organophosphorus chemistry
A concise synthetic route towards a new family of phosphorus-containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphor...
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| Hauptverfasser: | , , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2020
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| In: |
Chemistry - a European journal
Year: 2020, Jahrgang: 26, Heft: 58, Pages: 13157-13162 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.202002872 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/chem.202002872 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202002872 
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| Verfasserangaben: | Johannes D.R. Ascherl, Christian Neiß, Alexander Vogel, Jürgen Graf, Frank Rominger, Thomas Oeser, Frank Hampel, Andreas Görling, and Milan Kivala |
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| 520 | |a A concise synthetic route towards a new family of phosphorus-containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X-ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the development of organophosphorus functional materials with tailored properties upon further functionalization. | ||
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