Encapsulation of Au55 clusters within surface-supported metal-organic frameworks for catalytic reduction of 4-Nitrophenol
We demonstrate a facile approach to encapsulate ligand-stabilized Au55 clusters [Au55(PPh3)12Cl6] within highly oriented surface-supported metal-organic framework (SURMOF) thin films via liquid-phase epitaxy. The Au55 clusters were successfully loaded into the pores of SURMOF during their fabricatio...
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| Hauptverfasser: | , , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
December 16, 2020
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| In: |
ACS applied nano materials
Year: 2020, Jahrgang: 4, Heft: 1, Pages: 522-528 |
| ISSN: | 2574-0970 |
| DOI: | 10.1021/acsanm.0c02842 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acsanm.0c02842
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| Verfasserangaben: | Jinxuan Liu, Shahriar Heidrich, Jianxi Liu, Biao Guo, Michael Zharnikov, Ulrich Simon, Wolfgang Wenzel, Christof Wöll |
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| 520 | |a We demonstrate a facile approach to encapsulate ligand-stabilized Au55 clusters [Au55(PPh3)12Cl6] within highly oriented surface-supported metal-organic framework (SURMOF) thin films via liquid-phase epitaxy. The Au55 clusters were successfully loaded into the pores of SURMOF during their fabrication, which has been confirmed by X-ray diffraction, infrared spectroscopy, and ultraviolet-visible spectroscopy. Computational modeling reveals that there is a strong interaction between the Au55 core and the oligophenyl ligands of the MOF pore, leading to a removal of the PPH3 ligands. The stabilized Au55 clusters within SURMOF exhibit excellent catalytic activity for the reduction of 4-nitrophenol. | ||
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