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Gold-catalyzed synthesis of iodofulvenes

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We report the gold-catalyzed synthesis of highly functionalized iodofulvenes from iododialkynes under mild conditions. The catalytic cycle involves the formation of gold acetylides and vinylgold intermediates. These intermediates can then undergo an unprecedented iodine/gold exchange. This new pathw...

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Main Authors: Nösel, Pascal (Author) , Lauterbach, Tobias (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: May 7, 2013
In: Chemistry - a European journal
Year: 2013, Volume: 19, Issue: 26, Pages: 8634-8641
ISSN:1521-3765
DOI:10.1002/chem.201300507
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201300507
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201300507
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Author Notes:Pascal Nösel, Tobias Lauterbach, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi
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Gold-catalyzed synthesis of iodofulvenes


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