Poly(para-phenylene vinylene) and polynorbornadiene containing rod-coil block copoylmers via combination of acyclic diene metathesis and ring-opening metathesis polymerization
Poly(para-phenylene vinylene) (PPV) and its derivatives are important semiconducting polymers for organic electronics. Herein, an alkene metathesis approach to obtain PPVs is reported. Tri(iso propyl)silyl-substituted norbornadienes are employed as solubilizing agents. As PPV precursors divinylbenze...
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| Main Authors: | , , , |
|---|---|
| Format: | Article (Journal) Editorial |
| Language: | English |
| Published: |
April 8, 2013
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| In: |
Macromolecular rapid communications
Year: 2013, Volume: 34, Issue: 10, Pages: 873-878 |
| ISSN: | 1521-3927 |
| DOI: | 10.1002/marc.201300029 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/marc.201300029 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/marc.201300029 |
| Author Notes: | Michael Porz, Dominic Mäker, Kerstin Brödner, Uwe H.F. Bunz |
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| 520 | |a Poly(para-phenylene vinylene) (PPV) and its derivatives are important semiconducting polymers for organic electronics. Herein, an alkene metathesis approach to obtain PPVs is reported. Tri(iso propyl)silyl-substituted norbornadienes are employed as solubilizing agents. As PPV precursors divinylbenzene is used for acyclic diene metathesis and paracyclophane diene for a ring-opening metathesis polymerization-type approach. The resulting polymers are analyzed by gel permeation chromatography (GPC), UV-vis, fluorescence, and nuclear magnetic resonance (NMR) spectroscopy. All of the polymers show good solubility in common solvents. | ||
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