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TIPS-tetracene- and TIPS-pentacene-annulated poly(norbornadiene)s: synthesis and properties

The synthesis of tetracene- and pentacene-annulated norbornadienes, formed through the Diels-Alder reaction of a dehydroacene with cyclopentadiene is reported. Ring-opening metathesis polymerization (ROMP) leads to polymers that are investigated with respect to their physical, optical, and electroni...

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Main Authors: Porz, Michael (Author) , Paulus, Fabian (Author) , Höfle, Stefan (Author) , Lutz, Tobias (Author) , Lemmer, Uli (Author) , Colsmann, Alexander (Author) , Bunz, Uwe H. F. (Author)
Format: Article (Journal) Editorial
Language:English
Published: September 18, 2013
In: Macromolecular rapid communications
Year: 2013, Volume: 34, Issue: 20, Pages: 1611-1617
ISSN:1521-3927
DOI:10.1002/marc.201300557
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/marc.201300557
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/marc.201300557
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Author Notes:Michael Porz, Fabian Paulus, Stefan Höfle, Tobias Lutz, Uli Lemmer, Alexander Colsmann, Uwe H.F. Bunz
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Summary:The synthesis of tetracene- and pentacene-annulated norbornadienes, formed through the Diels-Alder reaction of a dehydroacene with cyclopentadiene is reported. Ring-opening metathesis polymerization (ROMP) leads to polymers that are investigated with respect to their physical, optical, and electronic properties by gel permeation chromatography (GPC), UV-vis spectroscopy, and cyclic voltammetry. The pentacene-containing polymer P1 is successfully integrated into an organic field-effect transistor (OFET); the tetracene-containing polymer P2 is integrated into an organic light-emitting diode (OLED).
Item Description:Gesehen am 07.12.2021
Physical Description:Online Resource
ISSN:1521-3927
DOI:10.1002/marc.201300557

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