Static conductance of nitrile-substituted oligophenylene and oligo(phenylene ethynylene) self-assembled monolayers studied by the mercury-drop method
Static charge transport (CT) properties of nitrile-substituted oligophenylenes and oligo(phenylene ethynylene)s (NC-OPh and NC-OPE, respectively) assembled via the thiolate anchor on gold substrates were measured by the mercury drop junction technique. The derived attenuation factors (β), viz. 0.53...
Gespeichert in:
| Hauptverfasser: | , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
November 20, 2013
|
| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2013, Jahrgang: 117, Heft: 48, Pages: 25556-25561 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/jp409366e |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jp409366e Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/jp409366e 
|
| Verfasserangaben: | Christine Joy Querebillo, Andreas Terfort, David L. Allara, and Michael Zharnikov |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1780921632 | ||
| 003 | DE-627 | ||
| 005 | 20220820092052.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 211210s2013 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/jp409366e |2 doi | |
| 035 | |a (DE-627)1780921632 | ||
| 035 | |a (DE-599)KXP1780921632 | ||
| 035 | |a (OCoLC)1341434682 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Querebillo, Christine Joy Uy |e VerfasserIn |0 (DE-588)1207580724 |0 (DE-627)169407997X |4 aut | |
| 245 | 1 | 0 | |a Static conductance of nitrile-substituted oligophenylene and oligo(phenylene ethynylene) self-assembled monolayers studied by the mercury-drop method |c Christine Joy Querebillo, Andreas Terfort, David L. Allara, and Michael Zharnikov |
| 264 | 1 | |c November 20, 2013 | |
| 300 | |a 6 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 10.12.2021 | ||
| 520 | |a Static charge transport (CT) properties of nitrile-substituted oligophenylenes and oligo(phenylene ethynylene)s (NC-OPh and NC-OPE, respectively) assembled via the thiolate anchor on gold substrates were measured by the mercury drop junction technique. The derived attenuation factors (β), viz. 0.53 ± 0.1 and 0.30 ± 0.08 Å-1 for the NC-OPh and NC-OPE monolayers, respectively, correlate well with the literature values for the analogous nonsubstituted systems, suggesting that the attachment of the nitrile group to the OPh or OPE backbone does not significantly affect their transport properties. This finding provides a basis for the use of the nitrile moiety as a resonantly addressable group and as specific charge injection site in the measurements of dynamic CT by resonant Auger electron spectroscopy. The comparison between the static and dynamic β values for the NC-OPh monolayers implies that the static value corresponds to nonresonant injection conditions. This suggests, potentially, that the static CT can be performed more efficiently by controlling the specific molecular orbitals into which charge carriers are injected. | ||
| 700 | 1 | |a Terfort, Andreas |e VerfasserIn |4 aut | |
| 700 | 1 | |a Allara, David L. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Zharnikov, Michael |e VerfasserIn |0 (DE-588)1118537629 |0 (DE-627)872019810 |0 (DE-576)479525889 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t The journal of physical chemistry. C, Energy, materials, and catalysis |d Washington, DC : Soc., 2007 |g 117(2013), 48, Seite 25556-25561 |h Online-Ressource |w (DE-627)519508645 |w (DE-600)2256522-X |w (DE-576)259487104 |x 1932-7455 |7 nnas |a Static conductance of nitrile-substituted oligophenylene and oligo(phenylene ethynylene) self-assembled monolayers studied by the mercury-drop method |
| 773 | 1 | 8 | |g volume:117 |g year:2013 |g number:48 |g pages:25556-25561 |g extent:6 |a Static conductance of nitrile-substituted oligophenylene and oligo(phenylene ethynylene) self-assembled monolayers studied by the mercury-drop method |
| 856 | 4 | 0 | |u https://doi.org/10.1021/jp409366e |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://pubs.acs.org/doi/10.1021/jp409366e |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20211210 | ||
| 993 | |a Article | ||
| 994 | |a 2013 | ||
| 998 | |g 1118537629 |a Zharnikov, Michael |m 1118537629:Zharnikov, Michael |d 120000 |d 120300 |e 120000PZ1118537629 |e 120300PZ1118537629 |k 0/120000/ |k 1/120000/120300/ |p 4 |y j | ||
| 999 | |a KXP-PPN1780921632 |e 4018436769 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"person":[{"role":"aut","roleDisplay":"VerfasserIn","display":"Querebillo, Christine Joy Uy","given":"Christine Joy Uy","family":"Querebillo"},{"given":"Andreas","family":"Terfort","role":"aut","display":"Terfort, Andreas","roleDisplay":"VerfasserIn"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Allara, David L.","given":"David L.","family":"Allara"},{"family":"Zharnikov","given":"Michael","roleDisplay":"VerfasserIn","display":"Zharnikov, Michael","role":"aut"}],"title":[{"title_sort":"Static conductance of nitrile-substituted oligophenylene and oligo(phenylene ethynylene) self-assembled monolayers studied by the mercury-drop method","title":"Static conductance of nitrile-substituted oligophenylene and oligo(phenylene ethynylene) self-assembled monolayers studied by the mercury-drop method"}],"language":["eng"],"recId":"1780921632","type":{"bibl":"article-journal","media":"Online-Ressource"},"note":["Gesehen am 10.12.2021"],"name":{"displayForm":["Christine Joy Querebillo, Andreas Terfort, David L. Allara, and Michael Zharnikov"]},"id":{"doi":["10.1021/jp409366e"],"eki":["1780921632"]},"origin":[{"dateIssuedDisp":"November 20, 2013","dateIssuedKey":"2013"}],"relHost":[{"title":[{"title":"The journal of physical chemistry","title_sort":"journal of physical chemistry","partname":"Energy, materials, and catalysis"}],"note":["Gesehen am 13.03.2023"],"disp":"Static conductance of nitrile-substituted oligophenylene and oligo(phenylene ethynylene) self-assembled monolayers studied by the mercury-drop methodThe journal of physical chemistry. C, Energy, materials, and catalysis","type":{"media":"Online-Ressource","bibl":"periodical"},"recId":"519508645","corporate":[{"role":"isb","display":"American Chemical Society","roleDisplay":"Herausgebendes Organ"}],"language":["eng"],"pubHistory":["111.2007 -"],"titleAlt":[{"title":"The journal of physical chemistry <Washington, DC> / C"},{"title":"Nanomaterials and interfaces"},{"title":"JPC C"},{"title":"JPCC"}],"part":{"extent":"6","text":"117(2013), 48, Seite 25556-25561","volume":"117","issue":"48","pages":"25556-25561","year":"2013"},"name":{"displayForm":["publ. weekly by the American Chemical Society"]},"origin":[{"publisherPlace":"Washington, DC","dateIssuedDisp":"2007-","dateIssuedKey":"2007","publisher":"Soc."}],"id":{"issn":["1932-7455"],"zdb":["2256522-X"],"eki":["519508645"]},"physDesc":[{"extent":"Online-Ressource"}]}],"physDesc":[{"extent":"6 S."}]} | ||
| SRT | |a QUEREBILLOSTATICCOND2020 | ||