Gold catalysis: highly functionalized cyclopentadienes prepared by intermolecular cyclization of ynamides and propargylic carboxylates
When an ynamide meets a gold carbenoid: Highly electrophilic gold carbenoids available from propargylic esters by means of 1,2-acyloxy migration open up new reaction pathways for ynamide gold chemistry. In this way highly functionalized cyclopentadiene derivatives become accessible (see scheme; EWG=...
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| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) Editorial |
| Sprache: | Englisch |
| Veröffentlicht: |
April 24, 2013
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| In: |
Angewandte Chemie. International edition
Year: 2013, Jahrgang: 52, Heft: 22, Pages: 5880-5884 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201301382 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201301382 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201301382 
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| Verfasserangaben: | Eva Rettenmeier, Andreas M. Schuster, Matthias Rudolph, Frank Rominger, Christoph A. Gade, and A. Stephen K. Hashmi |
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| 520 | |a When an ynamide meets a gold carbenoid: Highly electrophilic gold carbenoids available from propargylic esters by means of 1,2-acyloxy migration open up new reaction pathways for ynamide gold chemistry. In this way highly functionalized cyclopentadiene derivatives become accessible (see scheme; EWG=electron-withdrawing group). | ||
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