On the gold-catalyzed intramolecular 7-exo-trig hydroamination of allenes

Aniline derivatives with allene side tethers were tested as substrates for a gold-catalyzed 7-exo-trig hydroamination reaction. The nucleophilicity of the aniline derivatives plays an important role for the outcome of the reaction. While electron-deficient protecting groups at the nitrogen led to co...

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Main Authors: Pflästerer, Daniel (Author) , Dolbundalchok, Praphasiri (Author) , Rafique, Shahid (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format: Article (Journal)
Language:English
Published: April 30, 2013
In: Advanced synthesis & catalysis
Year: 2013, Volume: 355, Issue: 7, Pages: 1383-1393
ISSN:1615-4169
DOI:10.1002/adsc.201300154
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201300154
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201300154
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Author Notes:Daniel Pflästerer, Praphasiri Dolbundalchok, Shahid Rafique, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi