Accommodation of lattice mismatch in a thiol self-assembled monolayer
The structure of self-assembled monolayers (SAMs) of 3-(4′-(methylthio)-[1,1′-biphenyl]-4-yl)propane-1-thiol (CH3S(C6H4)2(CH2)3SH) formed on Au(111)/mica has been investigated by scanning tunneling microscopy (STM), high-resolution X-ray photoemission spectroscopy (HRXPS), near-edge X-ray absorption...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2013
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| In: |
The journal of physical chemistry. C, Energy, materials, and catalysis
Year: 2013, Jahrgang: 117, Heft: 9, Pages: 4647-4656 |
| ISSN: | 1932-7455 |
| DOI: | 10.1021/jp311927z |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/jp311927z Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jp311927z 
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| Verfasserangaben: | Zhe She, Dorothée Lahaye, Neil R. Champness, Michael Bühl, Hicham Hamoudi, Michael Zharnikov, and Manfred Buck |
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| 245 | 1 | 0 | |a Accommodation of lattice mismatch in a thiol self-assembled monolayer |c Zhe She, Dorothée Lahaye, Neil R. Champness, Michael Bühl, Hicham Hamoudi, Michael Zharnikov, and Manfred Buck |
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| 520 | |a The structure of self-assembled monolayers (SAMs) of 3-(4′-(methylthio)-[1,1′-biphenyl]-4-yl)propane-1-thiol (CH3S(C6H4)2(CH2)3SH) formed on Au(111)/mica has been investigated by scanning tunneling microscopy (STM), high-resolution X-ray photoemission spectroscopy (HRXPS), near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, and density functional theory (DFT) calculations. A highly crystalline monolayer terminated by thioether moieties is formed, which adopts a structure that differs from the previously studied CH3 terminated analogue with its 2√3 × √3 unit cell. An oblique 2√3 × √61 chiral unit cell containing 8 molecules is proposed. Accommodation of the substantial mismatch between the lattices of the SAM and substrate is explained by molecular design. Serving as a buffer layer, the alkane spacer decouples the SAM lattice, defined by the functionalized aromatic moieties, from the substrate. | ||
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