Understanding S-shaped current-voltage characteristics of organic solar cells: direct measurement of potential distributions by scanning Kelvin probe

We present a comparison of the potential distribution along the cross section of bilayer poly(3-hexylthiophene)/1-(3-methoxycarbonyl)propyl-1-phenyl[6,6]C61 (P3HT/PCBM) solar cells, which show normal and anomalous, S-shaped current-voltage (IV) characteristics. We expose the cross sections of the de...

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Hauptverfasser: Saive, Rebecca (VerfasserIn) , Müller, Christian (VerfasserIn) , Schinke, Janusz (VerfasserIn) , Lovrinčić, Robert (VerfasserIn) , Kowalsky, Wolfgang (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 11 December 2013
In: Applied physics letters
Year: 2013, Jahrgang: 103, Heft: 24, Pages: 1-3
ISSN:1077-3118
DOI:10.1063/1.4846615
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1063/1.4846615
Verlag, lizenzpflichtig, Volltext: https://aip.scitation.org/doi/10.1063/1.4846615
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Verfasserangaben:Rebecca Saive, Christian Mueller, Janusz Schinke, Robert Lovrincic, and Wolfgang Kowalsky
Beschreibung
Zusammenfassung:We present a comparison of the potential distribution along the cross section of bilayer poly(3-hexylthiophene)/1-(3-methoxycarbonyl)propyl-1-phenyl[6,6]C61 (P3HT/PCBM) solar cells, which show normal and anomalous, S-shaped current-voltage (IV) characteristics. We expose the cross sections of the devices with a focussed ion beam and measure them with scanning Kelvin probe microscopy. We find that in the case of S-shaped IV-characteristics, there is a huge potential drop at the PCBM/Al top contact, which does not occur in solar cells with normal IV-characteristics. This behavior confirms the assumption that S-shaped curves are caused by hindered charge transport at interfaces.
Beschreibung:Gesehen am 26.01.2022
Beschreibung:Online Resource
ISSN:1077-3118
DOI:10.1063/1.4846615