Gold-catalyzed synthesis of glyoxals by oxidation of terminal alkynes: one-pot synthesis of quinoxalines
From terminal alkynes to glyoxals: Terminal alkynes can be oxidized under mild conditions by the use of an N-oxide in the presence of a gold catalyst. The intermediate glyoxal derivatives can be transferred in a one-pot procedure to substituted quinoxalines (see scheme).
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2013
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| In: |
Chemistry - a European journal
Year: 2013, Jahrgang: 19, Heft: 21, Pages: 6576-6580 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201300518 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201300518 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201300518 |
| Verfasserangaben: | Shuai Shi, Tao Wang, Weibo Yang, Matthias Rudolph, and A. Stephen K. Hashmi |