Diastereoselective synthesis of 1,3-syn-oxazines via a tandem hemiaminalization and Tsuji-Trost reaction
A novel domino sequence for the rapid assembly of 1,3-syn-substituted oxazines is reported. Mechanistically, the one-pot procedure is based on a three-step sequential process involving a hemiaminalization and Tsuji-Trost reaction. The process generates up to two new stereogenic centers in a concise...
Gespeichert in:
| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) Editorial |
| Sprache: | Englisch |
| Veröffentlicht: |
18.02.2013
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| In: |
Synlett
Year: 2013, Jahrgang: 24, Heft: 5, Pages: 625-629 |
| ISSN: | 1437-2096 |
| DOI: | 10.1055/s-0032-1318300 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1055/s-0032-1318300 Verlag, lizenzpflichtig, Volltext: http://www.thieme-connect.de/DOI/DOI?10.1055/s-0032-1318300 
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| Verfasserangaben: | Bin Tang, Liang Wang, Dirk Menche |
MARC
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| 520 | |a A novel domino sequence for the rapid assembly of 1,3-syn-substituted oxazines is reported. Mechanistically, the one-pot procedure is based on a three-step sequential process involving a hemiaminalization and Tsuji-Trost reaction. The process generates up to two new stereogenic centers in a concise and convergent fashion from simple and readily available starting materials. | ||
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