Spin density distribution in iron(II) and cobalt(II) alkyl complexes containing 1,3-bis(2-pyridylimino)isoindolate ligands
Iron(II) and cobalt(II) alkyl complexes using tridentate bis(pyridylimino)isoindolates as ancillary ligands have been synthesized from the pyridine alkyl precursor complexes [(py)2Fe(CH2SiMe3)2] and [(py)2Co(CH2SiMe3)2]. The extremely air- and moisture-sensitive compounds were structurally character...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
January 22, 2013
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| In: |
Organometallics
Year: 2013, Jahrgang: 32, Heft: 3, Pages: 885-892 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om301198b |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om301198b Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/om301198b 
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| Verfasserangaben: | Désirée C. Sauer, Matthias Kruck, Hubert Wadepohl, Markus Enders, and Lutz H. Gade |
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| 245 | 1 | 0 | |a Spin density distribution in iron(II) and cobalt(II) alkyl complexes containing 1,3-bis(2-pyridylimino)isoindolate ligands |c Désirée C. Sauer, Matthias Kruck, Hubert Wadepohl, Markus Enders, and Lutz H. Gade |
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| 520 | |a Iron(II) and cobalt(II) alkyl complexes using tridentate bis(pyridylimino)isoindolates as ancillary ligands have been synthesized from the pyridine alkyl precursor complexes [(py)2Fe(CH2SiMe3)2] and [(py)2Co(CH2SiMe3)2]. The extremely air- and moisture-sensitive compounds were structurally characterized in the solid state by X-ray diffraction as well as in solution by paramagnetic NMR spectroscopy. It is demonstrated that the paramagnetic shifts in the 13C NMR spectra are dominated by strong Fermi-contact interactions. All 13C NMR signals can be assigned by correlation with DFT-calculated spin-density distributions. | ||
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