Dithieno(3,2-b:2′,3′-d)phospholes: a look back at the first decade
In this account, we describe our efforts in developing the chemistry of the highly luminescent dithieno[3,2-b:2′,3′-d]phosphole system over the last ten years. We provide an overview of the synthetic possibilities and the inherent tunability of the emission properties offered by this particular hete...
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| Main Authors: | , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
11. April 2013
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| In: |
Synlett
Year: 2013, Volume: 24, Issue: 8, Pages: 920-937 |
| ISSN: | 1437-2096 |
| DOI: | 10.1055/s-0032-1317804 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1055/s-0032-1317804 Verlag, lizenzpflichtig, Volltext: http://www.thieme-connect.de/DOI/DOI?10.1055/s-0032-1317804 
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| Author Notes: | Carlos Romero-Nieto, Thomas Baumgartner |
| Summary: | In this account, we describe our efforts in developing the chemistry of the highly luminescent dithieno[3,2-b:2′,3′-d]phosphole system over the last ten years. We provide an overview of the synthetic possibilities and the inherent tunability of the emission properties offered by this particular heterole. 1 Introduction 2 Synthesis and Properties of Dithieno[3,2-b:2′,3′-d]phospholes 3 Functionalization of Dithieno[3,2-b:2′,3′-d]phospholes 3.1 Phosphorus Functionalization 3.2 Functionalization at the 2- and 6-Positions 3.2.1 Symmetric Functionalization 3.2.2 Asymmetric Functionalization 3.3 Incorporation of Fused Rings onto the Main Scaffold 4 Photophysical Properties 5 Conclusions |
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| Item Description: | Gesehen am 03.02.2022 |
| Physical Description: | Online Resource |
| ISSN: | 1437-2096 |
| DOI: | 10.1055/s-0032-1317804 |