Complexation and thermodynamics of Cm(III) at high temperatures: the formation of (Cm(SO4)n)3-2n (n = 1,2,3) complexes at T=25 to 200 °C

The formation of [Cm(SO4)n]3−2n complexes (n = 1, 2, 3) in an aquatic solution is studied by time resolved laser fluorescence spectroscopy as a function of the ligand concentration, the ionic strength (NaClO4) and the temperature (25 to 200 °C). The experiments are performed in a custom-built high t...

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Bibliographic Details
Main Authors: Skerencak-Frech, Andrej (Author) , Panak, Petra (Author) , Fanghänel, Thomas (Author)
Format: Article (Journal)
Language:English
Published: 2013
In: Dalton transactions
Year: 2013, Volume: 42, Issue: 2, Pages: 542-549
ISSN:1477-9234
DOI:10.1039/C2DT31529G
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C2DT31529G
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2013/dt/c2dt31529g
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Author Notes:Andrej Skerencak, Petra J. Panak and Thomas Fanghänel
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Curium(III) luminescence spectroscopy as a tool for species determination by Schmidt, Moritz (Author) , Skerencak-Frech, Andrej (Author) , Panak, Petra (Author) , Huittinen, Nina (Author) ,


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