Complexation and thermodynamics of Cm(III) at high temperatures: the formation of (Cm(SO4)n)3-2n (n = 1,2,3) complexes at T=25 to 200 °C
The formation of [Cm(SO4)n]3−2n complexes (n = 1, 2, 3) in an aquatic solution is studied by time resolved laser fluorescence spectroscopy as a function of the ligand concentration, the ionic strength (NaClO4) and the temperature (25 to 200 °C). The experiments are performed in a custom-built high t...
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| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
2013
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| In: |
Dalton transactions
Year: 2013, Volume: 42, Issue: 2, Pages: 542-549 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/C2DT31529G |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C2DT31529G Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2013/dt/c2dt31529g |
| Author Notes: | Andrej Skerencak, Petra J. Panak and Thomas Fanghänel |
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