[Ge12{FeCp(CO)2} 8 {FeCp(CO)}2]: a Ge12 core resembles the arrangement of the high-pressure modification Germanium (II)
Similar yet different: The reaction of a GeBr solution with K[FeCp(CO)2] (Cp=η-C5H5) gives [Ge12FeCp(CO)28FeCp(CO)2] (1), whose oblong, highly cross-linked cluster core reveals a cut-out of the high-pressure solid-state structure of germanium (II) (see scheme). Mass spectrometric investigations on t...
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| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
January 3, 2013
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| In: |
Angewandte Chemie. International edition
Year: 2013, Jahrgang: 52, Heft: 6, Pages: 1834-1838 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201207224 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201207224 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201207224 
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| Verfasserangaben: | Christian Schenk, Florian Henke, and Andreas Schnepf |
MARC
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| 500 | |a Der gesamte Haupttitel steht in eckiger Klammer | ||
| 500 | |a Gesehen am 16.02.2022 | ||
| 520 | |a Similar yet different: The reaction of a GeBr solution with K[FeCp(CO)2] (Cp=η-C5H5) gives [Ge12FeCp(CO)28FeCp(CO)2] (1), whose oblong, highly cross-linked cluster core reveals a cut-out of the high-pressure solid-state structure of germanium (II) (see scheme). Mass spectrometric investigations on the gas-phase species [Ge6FeCp(CO)26FeCp(CO)]− (2) and theoretical calculations on 1 and 2 illuminate the formation of the metalloid cluster 1. | ||
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| 650 | 4 | |a metalloid cluster | |
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