Spin-state transition, magnetism and local crystal structure in Eu1-xCaxCoO3-δ
The doping series Eu1-xCaxCoO3-δ provides a rather peculiar way to study the spin-state transitions in cobalt-based complex oxides since partial substitution of Eu3+ ions by Ca2+ ions does not increase the mean valence of cobalt but is accompanied by appearance of oxygen vacancies in the ratio δ∼ x/...
Gespeichert in:
| Hauptverfasser: | , , , , , , , , , , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
March 22, 2013
|
| In: |
Journal of the Physical Society of Japan
Year: 2013, Jahrgang: 82, Heft: 4, Pages: 1-8 |
| ISSN: | 1347-4073 |
| DOI: | 10.7566/JPSJ.82.044714 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.7566/JPSJ.82.044714 Verlag, lizenzpflichtig, Volltext: https://journals.jps.jp/doi/10.7566/JPSJ.82.044714 
|
| Verfasserangaben: | Alexander N. Vasiliev, Tatyana M. Vasilchikova, Olga S. Volkova, Anton A. Kamenev, Andrey R. Kaul, Tatyana G. Kuzmova, Dmitry M. Tsymbarenko, Kirill A. Lomachenko, Alexander V. Soldatov, Sergey V. Streltsov, Jiunn-Yuan Lin, Cheng-Nan Kao, Jin-Ming Chen, Mahmoud Abdel-Hafiez, Anja Wolter, and Rüdiger Klingeler |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1793811075 | ||
| 003 | DE-627 | ||
| 005 | 20220820134239.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 220224s2013 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.7566/JPSJ.82.044714 |2 doi | |
| 035 | |a (DE-627)1793811075 | ||
| 035 | |a (DE-599)KXP1793811075 | ||
| 035 | |a (OCoLC)1341442023 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 29 |2 sdnb | ||
| 100 | 1 | |a Vasiliev, A. N. |e VerfasserIn |0 (DE-588)1197083464 |0 (DE-627)1678895369 |4 aut | |
| 245 | 1 | 0 | |a Spin-state transition, magnetism and local crystal structure in Eu1-xCaxCoO3-δ |c Alexander N. Vasiliev, Tatyana M. Vasilchikova, Olga S. Volkova, Anton A. Kamenev, Andrey R. Kaul, Tatyana G. Kuzmova, Dmitry M. Tsymbarenko, Kirill A. Lomachenko, Alexander V. Soldatov, Sergey V. Streltsov, Jiunn-Yuan Lin, Cheng-Nan Kao, Jin-Ming Chen, Mahmoud Abdel-Hafiez, Anja Wolter, and Rüdiger Klingeler |
| 246 | 3 | 3 | |a Spin-state transition, magnetism and local crystal structure in Eu 1-x Ca x CoO 3-delta |
| 264 | 1 | |c March 22, 2013 | |
| 300 | |a 8 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Im Titel ist "1-x", "x" und "3-δ" jeweils tiefgestellt | ||
| 500 | |a Gesehen am 24.02.2022 | ||
| 520 | |a The doping series Eu1-xCaxCoO3-δ provides a rather peculiar way to study the spin-state transitions in cobalt-based complex oxides since partial substitution of Eu3+ ions by Ca2+ ions does not increase the mean valence of cobalt but is accompanied by appearance of oxygen vacancies in the ratio δ∼ x/2. In the parent compound EuCoO3, the low spin (LS)-intermediate spin (IS) or high spin (HS) transition takes place at temperatures so high that the chemical decomposition prevents its direct observation. The substitution of Eu3+ by Ca2+ shifts the spin state transition to lower temperatures and the associated energy gap Δ in octahedrally-coordinated Co3+ ions changes from 1940 K in EuCoO3 to 1540 K in Eu0.9Ca0.1CoO2.95 and 1050 K in Eu0.8Ca0.2CoO2.9. Besides, each O2- vacancy reduces the local coordination of two neighboring Co3+ ions from octahedral to pyramidal thereby locally creating magnetically active sites which couple to dimers. These dimers form another gapped magnetic system with a very different energy scale, - D - dim - ∼3 - Ddim∼3 - K, on the background of the intrinsically non-magnetic lattice of octahedrally-coordinated low-spin Co3+ ions. | ||
| 650 | 4 | |a cobaltites | |
| 650 | 4 | |a local crystal structure | |
| 650 | 4 | |a magnetic susceptibility | |
| 650 | 4 | |a specific heat | |
| 650 | 4 | |a spin state transitions | |
| 650 | 4 | |a XANES | |
| 700 | 1 | |a Vasilchikova, Tatyana M. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Volkova, Olga S. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kamenev, Anton A. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kaul, Andrey R. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kuzmova, Tatyana G. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Tsymbarenko, Dmitry M. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Lomachenko, Kirill A. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Soldatov, Alexander V. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Streltsov, Sergey V. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Lin, Jiunn-Yuan |e VerfasserIn |4 aut | |
| 700 | 1 | |a Kao, Cheng-Nan |e VerfasserIn |4 aut | |
| 700 | 1 | |a Chen, Jin-Ming |e VerfasserIn |4 aut | |
| 700 | 1 | |a Abdel-Hafiez, Mahmoud |e VerfasserIn |4 aut | |
| 700 | 1 | |a Wolter, Anja |e VerfasserIn |4 aut | |
| 700 | 1 | |a Klingeler, Rüdiger |d 1969- |e VerfasserIn |0 (DE-588)128948736 |0 (DE-627)38613720X |0 (DE-576)187850720 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |a Nihon-Butsuri-Gakkai |t Journal of the Physical Society of Japan |d Tokyo : The Physical Society of Japan, 1946 |g 82(2013), 4, Artikel-ID 044714, Seite 1-8 |h Online-Ressource |w (DE-627)326979042 |w (DE-600)2042147-3 |w (DE-576)094140499 |x 1347-4073 |7 nnas |
| 773 | 1 | 8 | |g volume:82 |g year:2013 |g number:4 |g elocationid:044714 |g pages:1-8 |g extent:8 |a Spin-state transition, magnetism and local crystal structure in Eu1-xCaxCoO3-δ |
| 856 | 4 | 0 | |u https://doi.org/10.7566/JPSJ.82.044714 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://journals.jps.jp/doi/10.7566/JPSJ.82.044714 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20220224 | ||
| 993 | |a Article | ||
| 994 | |a 2013 | ||
| 998 | |g 128948736 |a Klingeler, Rüdiger |m 128948736:Klingeler, Rüdiger |d 130000 |d 130700 |e 130000PK128948736 |e 130700PK128948736 |k 0/130000/ |k 1/130000/130700/ |p 16 |y j | ||
| 999 | |a KXP-PPN1793811075 |e 4072086266 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"relHost":[{"language":["eng"],"note":["Gesehen am 17.09.2018","Fortsetzung der Druck-Ausgabe"],"title":[{"subtitle":"JPSJ online","title_sort":"Journal of the Physical Society of Japan","title":"Journal of the Physical Society of Japan"}],"pubHistory":["1.1946 -"],"recId":"326979042","part":{"text":"82(2013), 4, Artikel-ID 044714, Seite 1-8","issue":"4","volume":"82","extent":"8","year":"2013","pages":"1-8"},"titleAlt":[{"title":"JPSJ online"}],"disp":"Nihon-Butsuri-GakkaiJournal of the Physical Society of Japan","id":{"zdb":["2042147-3"],"eki":["326979042"],"issn":["1347-4073"]},"corporate":[{"display":"Nihon-Butsuri-Gakkai","role":"aut"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"physDesc":[{"extent":"Online-Ressource"}],"origin":[{"publisherPlace":"Tokyo","dateIssuedDisp":"1946-","publisher":"The Physical Society of Japan","dateIssuedKey":"1946"}]}],"recId":"1793811075","note":["Im Titel ist \"1-x\", \"x\" und \"3-δ\" jeweils tiefgestellt","Gesehen am 24.02.2022"],"title":[{"title":"Spin-state transition, magnetism and local crystal structure in Eu1-xCaxCoO3-δ","title_sort":"Spin-state transition, magnetism and local crystal structure in Eu1-xCaxCoO3-δ"}],"language":["eng"],"titleAlt":[{"title":"Spin-state transition, magnetism and local crystal structure in Eu 1-x Ca x CoO 3-delta"}],"person":[{"role":"aut","given":"A. N.","display":"Vasiliev, A. N.","family":"Vasiliev"},{"family":"Vasilchikova","display":"Vasilchikova, Tatyana M.","given":"Tatyana M.","role":"aut"},{"given":"Olga S.","role":"aut","family":"Volkova","display":"Volkova, Olga S."},{"family":"Kamenev","display":"Kamenev, Anton A.","given":"Anton A.","role":"aut"},{"display":"Kaul, Andrey R.","family":"Kaul","role":"aut","given":"Andrey R."},{"display":"Kuzmova, Tatyana G.","family":"Kuzmova","role":"aut","given":"Tatyana G."},{"family":"Tsymbarenko","display":"Tsymbarenko, Dmitry M.","given":"Dmitry M.","role":"aut"},{"given":"Kirill A.","role":"aut","family":"Lomachenko","display":"Lomachenko, Kirill A."},{"given":"Alexander V.","role":"aut","family":"Soldatov","display":"Soldatov, Alexander V."},{"family":"Streltsov","display":"Streltsov, Sergey V.","given":"Sergey V.","role":"aut"},{"display":"Lin, Jiunn-Yuan","family":"Lin","role":"aut","given":"Jiunn-Yuan"},{"given":"Cheng-Nan","role":"aut","family":"Kao","display":"Kao, Cheng-Nan"},{"family":"Chen","display":"Chen, Jin-Ming","given":"Jin-Ming","role":"aut"},{"display":"Abdel-Hafiez, Mahmoud","family":"Abdel-Hafiez","role":"aut","given":"Mahmoud"},{"given":"Anja","role":"aut","family":"Wolter","display":"Wolter, Anja"},{"display":"Klingeler, Rüdiger","family":"Klingeler","role":"aut","given":"Rüdiger"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"physDesc":[{"extent":"8 S."}],"id":{"doi":["10.7566/JPSJ.82.044714"],"eki":["1793811075"]},"name":{"displayForm":["Alexander N. Vasiliev, Tatyana M. Vasilchikova, Olga S. Volkova, Anton A. Kamenev, Andrey R. Kaul, Tatyana G. Kuzmova, Dmitry M. Tsymbarenko, Kirill A. Lomachenko, Alexander V. Soldatov, Sergey V. Streltsov, Jiunn-Yuan Lin, Cheng-Nan Kao, Jin-Ming Chen, Mahmoud Abdel-Hafiez, Anja Wolter, and Rüdiger Klingeler"]},"origin":[{"dateIssuedKey":"2013","dateIssuedDisp":"March 22, 2013"}]} | ||
| SRT | |a VASILIEVANSPINSTATET2220 | ||