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Martin’s phosphino-triol revisited: unexpected P-C bond cleavage reactions and their suppression via complexation of Al3+ and Sc3+

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A revised synthesis of Martin’s phosphino-triols (two derivatives) is reported. Once isolated, these thermally sensitive triols were shown to disassemble selectively via an unexpected P-C bond cleavage reaction. This degradation pathway was effectively suppressed via complexation of Al3+ and Sc3+. I...

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Main Authors: Mörsdorf, Jean-Marc (Author) , Bruckhoff, Tim (Author) , Matveeva, Regina (Author) , Rudin, Benjamin (Author) , Wadepohl, Hubert (Author) , Ballmann, Joachim (Author)
Format: Article (Journal)
Language:English
Published: November 30, 2021
In: Inorganic chemistry
Year: 2021, Volume: 60, Issue: 24, Pages: 19414-19420
ISSN:1520-510X
DOI:10.1021/acs.inorgchem.1c03232
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.inorgchem.1c03232
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Author Notes:Jean-Marc Mörsdorf, Tim Bruckhoff, Regina Matveeva, Benjamin Rudin, Hubert Wadepohl, and Joachim Ballmann

MARC

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