The high temperature heat capacity of NpO2

The enthalpy increments of pure NpO2 have been measured using drop calorimetry in the temperature range from (376 to 1770)K. The heat capacity was derived using the obtained data constrained to 66.20J·K−1·mol−1 at 298.15K taken from published low temperature measurements. The heat capacity of NpO2 d...

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Main Authors: Benes̆, Ondřej (Author) , Gotcu-Freis, P. (Author) , Schwörer, Felicitas (Author) , Konings, R. J. M. (Author) , Fanghänel, Thomas (Author)
Format: Article (Journal)
Language:English
Published: 2011
In: The journal of chemical thermodynamics
Year: 2011, Volume: 43, Issue: 5, Pages: 651-655
ISSN:1096-3626
DOI:10.1016/j.jct.2010.11.010
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jct.2010.11.010
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0021961410003484
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Author Notes:O. Beneš, P. Gotcu-Freis, F. Schwörer, R.J.M. Konings, Th. Fanghänel

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520 |a The enthalpy increments of pure NpO2 have been measured using drop calorimetry in the temperature range from (376 to 1770)K. The heat capacity was derived using the obtained data constrained to 66.20J·K−1·mol−1 at 298.15K taken from published low temperature measurements. The heat capacity of NpO2 determined in this study is given by the following equation:Cp,m0/(J·K-1·mol-1)=71.608+0.015845·(T/K)-900648·(T/K)-2. 
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