Single crystal growth and physical properties of superconducting ferro-pnictides Ba(Fe, Co)2As2 grown using self-flux and Bridgman techniques

We have employed the high temperature solutions growth technique and the Bridgman technique to grow cm-size high-quality single crystals of pristine BaFe2As2 (Ba122) and its Co-doped superconducting variants. In the first approach, self-flux (Fe, Co)As was used to achieve a homogeneous melt of compo...

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Hauptverfasser: Aswartham, Saicharan (VerfasserIn) , Nacke, C. (VerfasserIn) , Friemel, G. (VerfasserIn) , Leps, N. (VerfasserIn) , Wurmehl, S. (VerfasserIn) , Wizent, N. (VerfasserIn) , Hess, C. (VerfasserIn) , Klingeler, Rüdiger (VerfasserIn) , Behr, G. (VerfasserIn) , Singh, S. (VerfasserIn) , Büchner, B. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2011
In: Journal of crystal growth
Year: 2011, Jahrgang: 314, Heft: 1, Pages: 341-348
DOI:10.1016/j.jcrysgro.2010.11.149
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jcrysgro.2010.11.149
Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0022024810011309
Volltext
Verfasserangaben:S. Aswartham, C. Nacke, G. Friemel, N. Leps, S. Wurmehl, N. Wizent, C. Hess, R. Klingeler, G. Behr, S. Singh, B. Büchner

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245 1 0 |a Single crystal growth and physical properties of superconducting ferro-pnictides Ba(Fe, Co)2As2 grown using self-flux and Bridgman techniques  |c S. Aswartham, C. Nacke, G. Friemel, N. Leps, S. Wurmehl, N. Wizent, C. Hess, R. Klingeler, G. Behr, S. Singh, B. Büchner 
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520 |a We have employed the high temperature solutions growth technique and the Bridgman technique to grow cm-size high-quality single crystals of pristine BaFe2As2 (Ba122) and its Co-doped superconducting variants. In the first approach, self-flux (Fe, Co)As was used to achieve a homogeneous melt of composition Ba(Fe, Co)3.1As3.1 at T=1463K. The melt was then cooled slowly under a temperature gradient in a double-wall crucible assembly to obtain large and flux-free single crystals of Ba(Fe, Co)2As2. In the second approach, single crystals were grown directly from a stoichiometric Ba(Fe, Co)2As2 melt at T=1723K employing the Bridgman technique associated with a vertical tube furnace. Using both techniques single crystals with lateral dimensions up to 25×10mm2 and thickness up to 1mm were obtained. Details of the two methods are given and a comparative study of the magnetic and transport properties of the single crystals obtained using the two methods is presented. 
650 4 |a A1. Crystal morphology 
650 4 |a A2. Bridgman technique 
650 4 |a A2. Growth from high temperature solutions 
650 4 |a B1. Ferro-pnictides 
650 4 |a B2. Superconducting materials 
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700 1 |a Singh, S.  |e VerfasserIn  |4 aut 
700 1 |a Büchner, B.  |e VerfasserIn  |4 aut 
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