Hydrothiolation of donor-acceptor cyclopropanes through Er(OTf)3-promoted three-component ring-opening reaction

A novel ring-opening reaction of donor-acceptor cyclopropanes (DACs) through a one-pot three-component nucleophilic addition of amines, CS<sub>2</sub>, and DACs has been described. New γ-dithiocarbamate dialkyl malonate skeletons were obtained in up to 97% yield

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Bibliographic Details
Main Authors: Hosseini, S. Sina (Author) , Abdi, Aida (Author) , Nikbakht, Ali (Author) , Bijanzadeh, Hamid Reza (Author) , Rominger, Frank (Author) , Werz, Daniel B. (Author) , Balalaie, Saeed (Author)
Format: Article (Journal)
Language:English
Published: 03.02.2022
In: Synlett
Year: 2022, Volume: 33, Issue: 05, Pages: 468-472
ISSN:1437-2096
DOI:10.1055/a-1760-8951
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1055/a-1760-8951
Verlag, lizenzpflichtig, Volltext: http://www.thieme-connect.de/DOI/DOI?10.1055/a-1760-8951
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Author Notes:S. Sina Hosseini, Aida Abdi, Ali Nikbakht, Hamid Reza Bijanzadeh, Frank Rominger, Daniel B. Werz, Saeed Balalaie
Description
Summary:A novel ring-opening reaction of donor-acceptor cyclopropanes (DACs) through a one-pot three-component nucleophilic addition of amines, CS<sub>2</sub>, and DACs has been described. New γ-dithiocarbamate dialkyl malonate skeletons were obtained in up to 97% yield
Item Description:Im Titel ist die Zahl "3" tiefgestellt
Gesehen am 04.04.2022
Physical Description:Online Resource
ISSN:1437-2096
DOI:10.1055/a-1760-8951