Electron impact catalytic dissociation: Two-Bond Breaking by a Low-Energy Catalytic Electron
Upon impact of a low-energy electron on a neutral molecule, an intermediate metastable electron-molecule compound is formed. This species can undergo electron-catalyzed two-bond breaking or cycloelimination, as in the simplest case of the cyclobutane-ethylene conversion (see scheme). This mechanism...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2011
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| In: |
Angewandte Chemie. International edition
Year: 2011, Jahrgang: 50, Heft: 18, Pages: 4119-4122 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201005129 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201005129 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201005129 
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| Verfasserangaben: | Daly Davis, Victor P. Vysotskiy, Y. Sajeev, and Lorenz S. Cederbaum |
| Zusammenfassung: | Upon impact of a low-energy electron on a neutral molecule, an intermediate metastable electron-molecule compound is formed. This species can undergo electron-catalyzed two-bond breaking or cycloelimination, as in the simplest case of the cyclobutane-ethylene conversion (see scheme). This mechanism is illustrated for the quadricyclanone-norbornadienone cycloelimination reaction using ab initio methods, and its generality appears promising. |
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| Beschreibung: | Gesehen am 29.04.2022 |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.201005129 |