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Bicyclic cyclopentenones via the combination of an iridium-catalyzed allylic substitution with a diastereoselective intramolecular Pauson-Khand reaction

Enantioselective syntheses of bicyclic cyclopentenones are described. Key steps are an iridium-catalyzed allylic substitution and an intramolecular diastereoselective Pauson-Khand reaction. The diastereoselectivity of the Pauson-Khand reaction was found to be crucially dependent on the unit connecti...

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Main Authors: Farwick, Andreas (Author) , Engelhart, Jens U. (Author) , Tverskoy, Olena (Author) , Welter, Carolin (Author) , Umlauf, Quendolin A. (Author) , Rominger, Frank (Author) , Kerr, William J. (Author) , Helmchen, Günter (Author)
Format: Article (Journal)
Language:English
Published: 09 February 2011
In: Advanced synthesis & catalysis
Year: 2011, Volume: 353, Issue: 2/3, Pages: 349-370
ISSN:1615-4169
DOI:10.1002/adsc.201000706
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000706
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000706
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Author Notes:Andreas Farwick, Jens U. Engelhart, Olena Tverskoy, Carolin Welter, Quendolin A. Umlauf (née Stang), Frank Rominger, William J. Kerr, and Günter Helmchen

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