Valence tautomerism of p-block element compounds: an eligible phenomenon for main group catalysis?
Valence tautomerism has had a remarkable impact on several branches of transition metal chemistry. By switching between different valence tautomeric states, physicochemical properties and reactivities can be triggered reversibly. Is this phenomenon transferrable into the p-block - or is it already h...
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
January 27, 2022
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| In: |
European journal of inorganic chemistry
Year: 2022, Heft: 3, Pages: 1-7 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.202100871 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1002/ejic.202100871 Verlag, kostenfrei, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.202100871 
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| Verfasserangaben: | Lutz Greb |
MARC
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| 245 | 1 | 0 | |a Valence tautomerism of p-block element compounds |b an eligible phenomenon for main group catalysis? |c Lutz Greb |
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| 520 | |a Valence tautomerism has had a remarkable impact on several branches of transition metal chemistry. By switching between different valence tautomeric states, physicochemical properties and reactivities can be triggered reversibly. Is this phenomenon transferrable into the p-block - or is it already happening there? This Perspective collects observations of p-block element-ligand systems that might be assignable to valence tautomerism. Further, it discusses occurrences in p-block element compounds that exhibit the related effect of redox-induced electron transfer. As disclosed, the concept of valence tautomerism with p-block elements is at a very early stage. However, given the substantial disparity in the properties of those elements in different redox states, it might offer a valid extension for future developments in main group catalysis. | ||
| 650 | 4 | |a Electromerism | |
| 650 | 4 | |a Main group elements | |
| 650 | 4 | |a p-Block elements | |
| 650 | 4 | |a Redox chemistry | |
| 650 | 4 | |a Valence tautomerism | |
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