Synthesis of heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes via the isonitrile route
A convenient one-pot approach to bridged heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes is presented. The methodology exploits the graduated nucleophilicities of aliphatic and aromatic amines connected via an aromatic unit. This enables a straightforward access to bridg...
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| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
March 7, 2022
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| In: |
Organometallics
Year: 2022, Volume: 41, Issue: 6, Pages: 802-810 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/acs.organomet.2c00021 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.organomet.2c00021
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| Author Notes: | Martin C. Dietl, Vanessa Vethacke, Ali Keshavarzi, Florian F. Mulks, Frank Rominger, Matthias Rudolph, Ibraheem A.I. Mkhalid, and A. Stephen K. Hashmi |
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| 520 | |a A convenient one-pot approach to bridged heterobimetallic gold(I) palladium(II) bis(acyclic diaminocarbene) complexes is presented. The methodology exploits the graduated nucleophilicities of aliphatic and aromatic amines connected via an aromatic unit. This enables a straightforward access to bridged complexes from easily available isonitrile metal precursors. | ||
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