Linear magnetoelastic coupling and magnetic phase diagrams of the buckled-kagomé antiferromagnet Cu3Bi(SeO3)2O2Cl

Single crystals of Cu$$_3$$Bi(SeO$$_3$$)$$_2$$O$$_2$$Cl were investigated using high-resolution capacitance dilatometry in magnetic fields up to 15 T. Pronounced magnetoelastic coupling is found upon evolution of long-range antiferromagnetic order at $$T_{\mathrm {N}}$$ $$= 26.4(3)$$ K. Grüneisen a...

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Hauptverfasser: Spachmann, Sven (VerfasserIn) , Berdonosov, P. (VerfasserIn) , Markina, M. (VerfasserIn) , Vasiliev, A. (VerfasserIn) , Klingeler, Rüdiger (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 05 May 2022
In: Scientific reports
Year: 2022, Jahrgang: 12, Pages: 1-11
ISSN:2045-2322
DOI:10.1038/s41598-022-11368-5
Online-Zugang:Verlag, kostenfrei, Volltext: https://doi.org/10.1038/s41598-022-11368-5
Verlag, kostenfrei, Volltext: https://www.nature.com/articles/s41598-022-11368-5
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Verfasserangaben:S. Spachmann, P. Berdonosov, M. Markina, A. Vasiliev & R. Klingeler

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520 |a Single crystals of Cu$$_3$$Bi(SeO$$_3$$)$$_2$$O$$_2$$Cl were investigated using high-resolution capacitance dilatometry in magnetic fields up to 15 T. Pronounced magnetoelastic coupling is found upon evolution of long-range antiferromagnetic order at $$T_{\mathrm {N}}$$ $$= 26.4(3)$$ K. Grüneisen analysis reveals moderate effects of uniaxial pressure on $$T_{\mathrm {N}}$$, of 1.8(4) K/GPa, $$-0.62(15)$$ K/GPa and 0.33(10) K/GPa for   |p \parallel a$$, b, and c, respectively. Below 22 K Grüneisen scaling fails which implies the presence of competing interactions. The structural phase transition at $$T_{\mathrm {S}}$$ $$= 120.7(5)$$ K is much more sensitive to uniaxial pressure than $$T_{\mathrm {N}}$$, with strong effects of up to 27(3) K/GPa (  |p \parallel c$$). Magnetostriction and magnetization measurements reveal a linear magnetoelastic coupling for $$B\parallel c$$below $$T_{\mathrm {N}}$$, as well as a mixed phase behavior above the tricritical point around 0.4 T. An analysis of the critical behavior in zero-field points to three-dimensional (3D) Ising-like magnetic ordering. In addition, the magnetic phase diagrams for fields along the main crystalline axes are reported. 
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