Linear magnetoelastic coupling and magnetic phase diagrams of the buckled-kagomé antiferromagnet Cu3Bi(SeO3)2O2Cl
Single crystals of Cu$$_3$$Bi(SeO$$_3$$)$$_2$$O$$_2$$Cl were investigated using high-resolution capacitance dilatometry in magnetic fields up to 15 T. Pronounced magnetoelastic coupling is found upon evolution of long-range antiferromagnetic order at $$T_{\mathrm {N}}$$ $$= 26.4(3)$$ K. Grüneisen a...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
05 May 2022
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| In: |
Scientific reports
Year: 2022, Jahrgang: 12, Pages: 1-11 |
| ISSN: | 2045-2322 |
| DOI: | 10.1038/s41598-022-11368-5 |
| Online-Zugang: | Verlag, kostenfrei, Volltext: https://doi.org/10.1038/s41598-022-11368-5 Verlag, kostenfrei, Volltext: https://www.nature.com/articles/s41598-022-11368-5 |
| Verfasserangaben: | S. Spachmann, P. Berdonosov, M. Markina, A. Vasiliev & R. Klingeler |
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| 245 | 1 | 0 | |a Linear magnetoelastic coupling and magnetic phase diagrams of the buckled-kagomé antiferromagnet Cu3Bi(SeO3)2O2Cl |c S. Spachmann, P. Berdonosov, M. Markina, A. Vasiliev & R. Klingeler |
| 246 | 3 | 3 | |a Linear magnetoelastic coupling and magnetic phase diagrams of the buckled-kagomé antiferromagnet Cu 3 Bi(SeO 3) 2 O 2 Cl |
| 246 | 3 | 3 | |a Linear magnetoelastic coupling and magnetic phase diagrams of the buckled-kagomé antiferromagnet Cu three Bi(SeO three) two O two Cl |
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| 520 | |a Single crystals of Cu$$_3$$Bi(SeO$$_3$$)$$_2$$O$$_2$$Cl were investigated using high-resolution capacitance dilatometry in magnetic fields up to 15 T. Pronounced magnetoelastic coupling is found upon evolution of long-range antiferromagnetic order at $$T_{\mathrm {N}}$$ $$= 26.4(3)$$ K. Grüneisen analysis reveals moderate effects of uniaxial pressure on $$T_{\mathrm {N}}$$, of 1.8(4) K/GPa, $$-0.62(15)$$ K/GPa and 0.33(10) K/GPa for |p \parallel a$$, b, and c, respectively. Below 22 K Grüneisen scaling fails which implies the presence of competing interactions. The structural phase transition at $$T_{\mathrm {S}}$$ $$= 120.7(5)$$ K is much more sensitive to uniaxial pressure than $$T_{\mathrm {N}}$$, with strong effects of up to 27(3) K/GPa ( |p \parallel c$$). Magnetostriction and magnetization measurements reveal a linear magnetoelastic coupling for $$B\parallel c$$below $$T_{\mathrm {N}}$$, as well as a mixed phase behavior above the tricritical point around 0.4 T. An analysis of the critical behavior in zero-field points to three-dimensional (3D) Ising-like magnetic ordering. In addition, the magnetic phase diagrams for fields along the main crystalline axes are reported. | ||
| 650 | 4 | |a Ferroelectrics and multiferroics | |
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| 650 | 4 | |a Magnetic properties and materials | |
| 650 | 4 | |a Materials for devices | |
| 650 | 4 | |a Phase transitions and critical phenomena | |
| 700 | 1 | |a Berdonosov, P. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Markina, M. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Vasiliev, A. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Klingeler, Rüdiger |d 1969- |e VerfasserIn |0 (DE-588)128948736 |0 (DE-627)38613720X |0 (DE-576)187850720 |4 aut | |
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