Synthesis of heterobimetallic Zn/Co carbamates: single-source precursors of nanosized magnetic oxides under mild conditions

Tetrameric Zn alkyl carbamates [ZnR(O2CNR′2)]4 (R = Me or Et, R′ = iPr) have been synthesized from alkylzinc amides and CO2. The reaction of these carbamates with specially designed CoII complexes afforded new heterobimetallic (Zn/Co) carbamate complexes. The thermal decomposition of these single-so...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Domide, Dan (VerfasserIn) , Walter, Olaf (VerfasserIn) , Behrens, Silke (VerfasserIn) , Kaifer, Elisabeth (VerfasserIn) , Himmel, Hans-Jörg (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 17 January 2011
In: European journal of inorganic chemistry
Year: 2011, Heft: 6, Pages: 860-867
ISSN:1099-0682
DOI:10.1002/ejic.201001095
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.201001095
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201001095
Volltext
Verfasserangaben:Dan Domide, Olaf Walter, Silke Behrens, Elisabeth Kaifer, and Hans-Jörg Himmel

MARC

LEADER 00000caa a2200000 c 4500
001 1807292533
003 DE-627
005 20241209094034.0
007 cr uuu---uuuuu
008 220620s2011 xx |||||o 00| ||eng c
024 7 |a 10.1002/ejic.201001095  |2 doi 
035 |a (DE-627)1807292533 
035 |a (DE-599)KXP1807292533 
035 |a (OCoLC)1341461526 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Domide, Dan  |e VerfasserIn  |0 (DE-588)143061739  |0 (DE-627)641869398  |0 (DE-576)334840260  |4 aut 
245 1 0 |a Synthesis of heterobimetallic Zn/Co carbamates  |b single-source precursors of nanosized magnetic oxides under mild conditions  |c Dan Domide, Olaf Walter, Silke Behrens, Elisabeth Kaifer, and Hans-Jörg Himmel 
246 3 3 |a Synthesis of heterobimetallic zinc cobalt carbamates 
264 1 |c 17 January 2011 
300 |a 8 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 20.06.2022 
520 |a Tetrameric Zn alkyl carbamates [ZnR(O2CNR′2)]4 (R = Me or Et, R′ = iPr) have been synthesized from alkylzinc amides and CO2. The reaction of these carbamates with specially designed CoII complexes afforded new heterobimetallic (Zn/Co) carbamate complexes. The thermal decomposition of these single-source precursors under mild conditions (200-300 °C) led to magnetic mixed-metal oxide nanoparticles. Two phases were identified that are isostructural with ZnO (wurtzite phase) and CoO (cubic rock salt structure), but both contain Zn and Co in varying molar ratios. The particles with the ZnO-type structure have a mean average size of 7.7 nm, whereas the particles with the CoO-type structure are much larger (ca. 48 nm). 
650 4 |a Carbamates 
650 4 |a Cobalt 
650 4 |a Heterobimetallic complexes 
650 4 |a Nanostructures 
650 4 |a Zinc 
700 1 |a Walter, Olaf  |e VerfasserIn  |4 aut 
700 1 |a Behrens, Silke  |d 1969-  |e VerfasserIn  |0 (DE-588)120297752  |0 (DE-627)696543656  |0 (DE-576)292145772  |4 aut 
700 1 |a Kaifer, Elisabeth  |e VerfasserIn  |0 (DE-588)1020547898  |0 (DE-627)691256624  |0 (DE-576)166913820  |4 aut 
700 1 |a Himmel, Hans-Jörg  |d 1970-  |e VerfasserIn  |0 (DE-588)120090368  |0 (DE-627)080439683  |0 (DE-576)292036159  |4 aut 
773 0 8 |i Enthalten in  |t European journal of inorganic chemistry  |d Weinheim : Wiley-VCH, 1998  |g (2011), 6, Seite 860-867  |h Online-Ressource  |w (DE-627)269534520  |w (DE-600)1475009-0  |w (DE-576)077884671  |x 1099-0682  |7 nnas  |a Synthesis of heterobimetallic Zn/Co carbamates single-source precursors of nanosized magnetic oxides under mild conditions 
773 1 8 |g year:2011  |g number:6  |g pages:860-867  |g extent:8  |a Synthesis of heterobimetallic Zn/Co carbamates single-source precursors of nanosized magnetic oxides under mild conditions 
856 4 0 |u https://doi.org/10.1002/ejic.201001095  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201001095  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20220620 
993 |a Article 
994 |a 2011 
998 |g 120090368  |a Himmel, Hans-Jörg  |m 120090368:Himmel, Hans-Jörg  |d 120000  |d 120200  |e 120000PH120090368  |e 120200PH120090368  |k 0/120000/  |k 1/120000/120200/  |p 5  |y j 
998 |g 1020547898  |a Kaifer, Elisabeth  |m 1020547898:Kaifer, Elisabeth  |d 120000  |d 120200  |e 120000PK1020547898  |e 120200PK1020547898  |k 0/120000/  |k 1/120000/120200/  |p 4 
998 |g 120297752  |a Behrens, Silke  |m 120297752:Behrens, Silke  |d 120000  |e 120000PB120297752  |k 0/120000/  |p 3 
999 |a KXP-PPN1807292533  |e 4152976608 
BIB |a Y 
SER |a journal 
JSO |a {"person":[{"display":"Domide, Dan","family":"Domide","given":"Dan","role":"aut"},{"given":"Olaf","role":"aut","display":"Walter, Olaf","family":"Walter"},{"role":"aut","given":"Silke","family":"Behrens","display":"Behrens, Silke"},{"display":"Kaifer, Elisabeth","family":"Kaifer","role":"aut","given":"Elisabeth"},{"role":"aut","given":"Hans-Jörg","family":"Himmel","display":"Himmel, Hans-Jörg"}],"language":["eng"],"titleAlt":[{"title":"Synthesis of heterobimetallic zinc cobalt carbamates"}],"origin":[{"dateIssuedDisp":"17 January 2011","dateIssuedKey":"2011"}],"note":["Gesehen am 20.06.2022"],"title":[{"subtitle":"single-source precursors of nanosized magnetic oxides under mild conditions","title_sort":"Synthesis of heterobimetallic Zn/Co carbamates","title":"Synthesis of heterobimetallic Zn/Co carbamates"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"name":{"displayForm":["Dan Domide, Olaf Walter, Silke Behrens, Elisabeth Kaifer, and Hans-Jörg Himmel"]},"physDesc":[{"extent":"8 S."}],"recId":"1807292533","relHost":[{"disp":"Synthesis of heterobimetallic Zn/Co carbamates single-source precursors of nanosized magnetic oxides under mild conditionsEuropean journal of inorganic chemistry","type":{"bibl":"periodical","media":"Online-Ressource"},"title":[{"title_sort":"European journal of inorganic chemistry","title":"European journal of inorganic chemistry"}],"pubHistory":["Volume 1998, Issue 1 (January 1998)-"],"origin":[{"publisher":"Wiley-VCH","dateIssuedKey":"1998","dateIssuedDisp":"1998-","publisherPlace":"Weinheim"}],"note":["Gesehen am 27.02.24","Fortsetzung der Druck-Ausgabe"],"id":{"eki":["269534520"],"zdb":["1475009-0"],"issn":["1099-0682"],"doi":["10.1002/(ISSN)1099-0682c"]},"physDesc":[{"extent":"Online-Ressource"}],"recId":"269534520","part":{"year":"2011","pages":"860-867","issue":"6","text":"(2011), 6, Seite 860-867","extent":"8"},"language":["eng"]}],"id":{"eki":["1807292533"],"doi":["10.1002/ejic.201001095"]}} 
SRT |a DOMIDEDANWSYNTHESISO1720