Gold catalysis: hydrolysis of Di(alkoxy)carbenium ion intermediates as a sensor for the electronic properties of gold(I) complexes

Six different cationic gold(I) complexes LAu+ were converted to the corresponding di(alkoxy)carbenium ions by reaction with ethyl 2,5-dimethylhexa-2,3-dienoate. These conversions were monitored by in situ IR spectroscopy; at room temperature they proceeded in only a few seconds. The ligands L are ba...

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Bibliographic Details

Main Authors:	Döpp, René (Author) , Lothschütz, Christian (Author) , Wurm, Thomas (Author) , Pernpointner, Markus (Author) , Keller, Sascha (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format:	Article (Journal)
Language:	English
Published:	October 12, 2011
In:	Organometallics Year: 2011, Volume: 30, Issue: 21, Pages: 5894-5903
ISSN:	1520-6041
DOI:	10.1021/om200735c
Online Access:	Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om200735c Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/om200735c#
Author Notes:	René Döpp, Christian Lothschütz, Thomas Wurm, Markus Pernpointner, Sascha Keller, Frank Rominger, and A. Stephen K. Hashmi