Bis(pyridylimino)isoindolato-iridium complexes as epoxidation catalysts for alkenes
The reaction of the sodium salts of ligands 1a,b (1a = 1,3-bis(2-(5-(3,5-xylyl)pyridyl)imino)-5,6-dimethylisoindole, 1b = 1,3-bis(2-(4-tert-butylpyridyl)imino)-5,6-dimethylisoindole) with [Ir(μ-Cl)(COD)]2 (COD = cyclooctadiene) and [Ir(μ-Cl)(C2H4)2]2 afforded the corresponding isoindolato complexes...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
4 January 2011
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| In: |
Organometallics
Year: 2011, Jahrgang: 30, Heft: 3, Pages: 379-382 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om1010116 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om1010116
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| Verfasserangaben: | José A. Camerano, Christoph Sämann, Hubert Wadepohl, and Lutz H. Gade |
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| 245 | 1 | 0 | |a Bis(pyridylimino)isoindolato-iridium complexes as epoxidation catalysts for alkenes |c José A. Camerano, Christoph Sämann, Hubert Wadepohl, and Lutz H. Gade |
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| 520 | |a The reaction of the sodium salts of ligands 1a,b (1a = 1,3-bis(2-(5-(3,5-xylyl)pyridyl)imino)-5,6-dimethylisoindole, 1b = 1,3-bis(2-(4-tert-butylpyridyl)imino)-5,6-dimethylisoindole) with [Ir(μ-Cl)(COD)]2 (COD = cyclooctadiene) and [Ir(μ-Cl)(C2H4)2]2 afforded the corresponding isoindolato complexes [{BPI(1a,b)}IrI(COD)] (2a,b) and [{BPI(1a,b)}IrI(C2H4)2] (3a,b), respectively. The catalytic activity of the complexes 2a,b was tested in the epoxidation of a wide range of non-electron-rich olefins, using PPO (PPO = 3-phenyl-2-(phenylsulfonyl)-1,2-oxaziridine) as oxidizing agent, giving the corresponding epoxides in moderate to high yields. | ||
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