Synthesis, characterization, and photocatalytic properties of core/shell mesoporous silica nanospheres supporting nanocrystalline titania

The facile bulk synthesis of silica nanospheres makes them an attractive support for the transport of chemical compounds such as nanocrystalline titanium dioxide. In this contribution we present a promising route for the synthesis of mesoporous silica nanospheres (m-SiO2) with diameter in range 200...

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Main Authors: Cendrowski, Krysztof (Author) , Chen, X. (Author) , Zielinska, B. (Author) , Kalenczuk, R. J. (Author) , Rümmeli, M. H. (Author) , Büchner, B. (Author) , Klingeler, Rüdiger (Author) , Borowiak-Palen, E. (Author)
Format: Article (Journal)
Language:English
Published: 19 March 2011
In: Journal of nanoparticle research
Year: 2011, Volume: 13, Issue: 11, Pages: 5899-5908
ISSN:1572-896X
DOI:10.1007/s11051-011-0307-1
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1007/s11051-011-0307-1
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Author Notes:K. Cendrowski, X. Chen, B. Zielinska, R.J. Kalenczuk, M.H. Rümmeli, B. Büchner, R. Klingeler, E. Borowiak-Palen

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520 |a The facile bulk synthesis of silica nanospheres makes them an attractive support for the transport of chemical compounds such as nanocrystalline titanium dioxide. In this contribution we present a promising route for the synthesis of mesoporous silica nanospheres (m-SiO2) with diameter in range 200 nm, which are ideal supports for nanocrystalline titanium dioxide (TiO2). The detailed microscopic and spectroscopic characterizations of core/shell structure (m-SiO2/TiO2) were conducted. Moreover, the photocatalytic potential of the nanostructures was investigated via phenol decomposition and hydrogen generation. A clear enhancement of photoactivity in both reactions as compared to commercial TiO2-Degussa P25 catalyst is detected. 
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