Gold catalysis: alkyl migration in the addition of alcohols to nitriles

Benzhydroles and nitriles upon gold-catalysed conversion deliver symmetrical ethers and/or N-substituted carboxylic amides. While with most phosphane ligands tested, the dominating product is always the ether, with the trimesitylene ligand the amides are the major products. The reaction conditions a...

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Bibliographic Details
Main Authors: Ibrahim, Nada (Author) , Hashmi, A. Stephen K. (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 15 February 2011
In: Advanced synthesis & catalysis
Year: 2011, Volume: 353, Issue: 2-3, Pages: 461-468
ISSN:1615-4169
DOI:10.1002/adsc.201000779
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000779
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000779
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Author Notes:Nada Ibrahim, A. Stephen K. Hashmi, and Frank Rominger
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Gold catalysis: alkyl migration in the addition of alcohols to nitriles by Ibrahim, Nada (Author) , Hashmi, A. Stephen K. (Author) , Rominger, Frank (Author) ,


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