Gold catalysis: alkyl migration in the addition of alcohols to nitriles
Benzhydroles and nitriles upon gold-catalysed conversion deliver symmetrical ethers and/or N-substituted carboxylic amides. While with most phosphane ligands tested, the dominating product is always the ether, with the trimesitylene ligand the amides are the major products. The reaction conditions a...
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| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
15 February 2011
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| In: |
Advanced synthesis & catalysis
Year: 2011, Volume: 353, Issue: 2-3, Pages: 461-468 |
| ISSN: | 1615-4169 |
| DOI: | 10.1002/adsc.201000779 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/adsc.201000779 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.201000779 |
| Author Notes: | Nada Ibrahim, A. Stephen K. Hashmi, and Frank Rominger |
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